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- Publisher
- Royal Society of Chemistry
- Copyright
- This journal is © The Royal Society of Chemistry
- ISSN
- 1477-9226
- eISSN
- 1477-9234
- DOI
- 10.1039/b902524c
- pmid
- 19488434
- Publisher site
- See Article on Publisher Site
Abstract
Iron complexes containing hydrazido(1−) and diazene ligands were investigated as potential intermediates in the reduction of N2 to NH3. Generation of cis-[Fe(DMeOPrPE)2(η2-N2H3)]+ and cis-Fe(DMeOPrPE)2(η2-N2H2) (DMeOPrPE = 1,2-bis(dimethoxypropylphosphino)ethane) was achieved by addition of base to cis-[Fe(DMeOPrPE)2(N2H4)]2+. The hydrazine, hydrazido(1−), and diazene complexes can be interconverted by protonation/deprotonation reactions.
Journal
Dalton Transactions – Royal Society of Chemistry
Published: Jun 2, 2009