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- Publisher
- Wiley
- Copyright
- Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- DOI
- 10.1002/anie.200701188
- pmid
- 17600810
- Publisher site
- See Article on Publisher Site
Abstract
Taking hold: Monoanionic tris(phosphino)silyl ligands ((SiPR3)=((2‐R2PC6H4)3Si)−) stabilize unusual five‐coordinate FeI complexes. The silane (SiPPh3)H reacts with mesityliron(II) to give ((SiPPh3)FeIIMes), which displays a CH agostic interaction. Treatment with HCl and reduction affords the terminally bonded FeIN2 complex ((SiPPh3)FeN2) (see scheme; structures show only donor atoms of (SiPPh3)), which yields hydrazine under protolytic conditions.
Journal
Angewandte Chemie International Edition – Wiley
Published: Jul 23, 2007