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- Publisher
- Wiley
- Copyright
- Copyright © 2001 Wiley Subscription Services
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- DOI
- 10.1002/1521-3773(20010302)40:5<958::AID-ANIE958>3.0.CO;2-4
- Publisher site
- See Article on Publisher Site
Abstract
A new reaction: A ruthenium‐catalyzed transfer of an alkyl group from a trialkylamine to the α‐carbon atom of a ketone leads in good yields to α‐alkylated ketones (Eq. (1)). The reaction is applicable to a wide range of alkyl(alkyl), alkyl(aryl), and cyclic ketones, and in the case of unsymmetrical ketones it takes place regioselectively at the less hindered α‐position.
Journal
Angewandte Chemie International Edition – Wiley
Published: Jan 2, 2001
Keywords: ; ; ; ;