Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines
Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines
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1980-01-01 00:00:00
We have found that several transition metal cluster compounds act as homogeneous catalyst precursors in alkyl exchange reactions of tertiary amines; treatment of mixtures of EtN and PrN with either Ru(CO), Os(CO), or Ir(CO) and water leads to very efficient alkyl exchange.
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Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines
We have found that several transition metal cluster compounds act as homogeneous catalyst precursors in alkyl exchange reactions of tertiary amines; treatment of mixtures of EtN and PrN with either Ru(CO), Os(CO), or Ir(CO) and water leads to very efficient alkyl exchange.
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