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Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines

Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines We have found that several transition metal cluster compounds act as homogeneous catalyst precursors in alkyl exchange reactions of tertiary amines; treatment of mixtures of EtN and PrN with either Ru(CO), Os(CO), or Ir(CO) and water leads to very efficient alkyl exchange. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png

Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines

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Royal Society of Chemistry — Jan 1, 1980

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Royal Society of Chemistry
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Abstract

We have found that several transition metal cluster compounds act as homogeneous catalyst precursors in alkyl exchange reactions of tertiary amines; treatment of mixtures of EtN and PrN with either Ru(CO), Os(CO), or Ir(CO) and water leads to very efficient alkyl exchange.

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