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References (10)
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T. Wallington (1986)
Kinetics of the gas phase reaction of OH radicals with pyrrole and thiopheneInternational Journal of Chemical Kinetics, 18
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T. Wallington, M. Kurylo (1987)
Flash photolysis resonance fluorescence investigation of the gas-phase reactions of hydroxyl radicals with a series of aliphatic ketones over the temperature range 240-440 KThe Journal of Physical Chemistry, 91
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T. Wallington, Renzhang Liu, P. Dagaut, M. Kurylo (1987)
The gas phase reactions of hydroxyl radicals with a series of aliphatic ethers over the temperature range 240–440 KInternational Journal of Chemical Kinetics, 20
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T. Wallington, Douglas Neuman, M. Kurylo (1987)
Kinetics of the gas phase reaction of hydroxyl radicals with ethane, benzene, and a series of halogenated benzenes over the temperature range 234–438 KInternational Journal of Chemical Kinetics, 19
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R. Atkinson (1986)
Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditionsChemical Reviews, 86
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M. Kurylo, W. Braun (1976)
Flash photolysis resonance fluorescence study of the reaction Cl + O3 → ClO + O2 over the temperature range 213–298 KChemical Physics Letters, 37
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R. Atkinson (1987)
A structure-activity relationship for the estimation of rate constants for the gas-phase reactions of OH radicals with organic compoundsInternational Journal of Chemical Kinetics, 19
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(1988)
Rate constants for the gas phase reactions of OH with C5 through C7 aliphatic alcohols and ethers: Predicted and experimental values -
F. Witte, E. Urbanik, C. Zetzsch (1986)
Temperature dependence of the rate constants for the addition of hydroxyl to benzene and to some monosubstituted aromatics (aniline, bromobenzene, and nitrobenzene) and the unimolecular decay of the adducts. Part 2. Kinetics into a quasi-equilibriumThe Journal of Physical Chemistry, 90
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The temperature dependence of the rate constant for the reaction of hydroxyl radicals With nitric acidJournal of Geophysical Research, 87
- Publisher
- Wiley
- Copyright
- Copyright © 1988 John Wiley & Sons, Inc.
- ISSN
- 0538-8066
- eISSN
- 1097-4601
- DOI
- 10.1002/kin.550200704
- Publisher site
- See Article on Publisher Site
Abstract
Absolute rate constants were determined at 298 K for the gas phase reactions of hydroxyl radicals with several C5 through C7 aliphatic alcohols and ethers using the flash photolysis resonance fluorescence technique. The values obtained (in units of 10−12 cm3 molecule−1 s−1) were: 3‐methyl‐2‐butanol, (12.4 ± 0.7); 2‐pentanol, (11.8 ± 0.8); 3‐pentanol, (12.2 ± 0.7); cyclopentanol, (10.7 ± 0.7); 1‐hexanol, (12.4 ± 0.7); 2‐hexanol, (12.1 ± 0.7); 1‐heptanol, (13.6 ± 1.3); methyl‐n‐butylether, (16.4 ± 0.6); ethyl‐n‐butylether, (22.8 ± 0.9); ethyl‐t‐butylether, (8.12 ± 0.32); and methyl‐t‐amylether, (7.91 ± 0.42). These results are discussed in terms of group reactivities in such molecules and are compared with values estimated from an additive structure‐reactivity index.
Journal
International Journal of Chemical Kinetics – Wiley
Published: Jul 1, 1988