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- Publisher
- Wiley
- Copyright
- Copyright © 2002 Wiley Subscription Services
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- DOI
- 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO;2-Y
- Publisher site
- See Article on Publisher Site
Abstract
Breathtaking are the highly magnetic and porous vanadocarboxylates (TN=95 K) MIL‐47as (left) and evacuated MIL‐47 (right) that exhibit three‐dimensional large‐pore structures built up from infinite chains of corner‐sharing VIIIO4(OH)2 (MIL‐47as) and VIVO6 (MIL‐47) octahedra linked by rigid terephthalate anions. The reversible adsorption–desorption corresponds to a breathing of the structure. The high TN value results from the combination of magnetic chains with the presence of the π electrons of the terephthalate.
Journal
Angewandte Chemie International Edition – Wiley
Published: Jan 18, 2002
Keywords: ; ; ; ;