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References (8)
-
Jeffrey Ellison, Karin Ruhlandt-Senge, Philip Power (1994)
Synthese und Charakterisierung von Thiolatokomplexen mit zweifach koordiniertem Eisen(II)Angewandte Chemie, 106
-
Xiaowei Li, W. Pennington, G. Robinson (1995)
Metallic System with Aromatic Character. Synthesis and Molecular Structure of Na2[[(2,4,6-Me3C6H2)2C6H3]Ga]3 The First CyclogallaneJournal of the American Chemical Society, 117
-
Daniele Hoffmann, W. Bauer, F. Hampel, N. Hommes, P. Schleyer, P. Otto, U. Pieper, D. Stalke, D. Wright, R. Snaith (1994)
.eta.3 and .eta.6 Bridging cations in the N,N,N',N'',N''-pentamethyldiethylenetriamine-solvated complexes of benzylpotassium and benzylrubidium: an x-ray, NMR, and MO studyJournal of the American Chemical Society, 116
-
A. Sekiguchi, H. Yamazaki, C. Kabuto, H. Sakurai, S. Nagase (1995)
Cyclotrigermenes: A New Unsaturated Ring SystemChemInform, 26
-
Daniele Hoffmann, D. Bauer, P. Schleyer, U. Pieper, D. Stalke (1993)
Cation-induced structural alterations in the organo alkali metal derivatives of triphenylmethane: a combined x-ray and NMR study of the potassium-cesium saltsOrganometallics, 12
-
Xiaowei Li, Yaoming Xie, P. Schreiner, Kevin Gripper, R. Crittendon, C. Campana, H. Schaefer, G. Robinson (1996)
Cyclogallanes and Metalloaromaticity. Synthesis and Molecular Structure of Dipotassium Tris((2,6-dimesitylphenyl)cyclogallene), K2[(Mes2C6H3)Ga]3 (Mes = 2,4,6-Me3C6H2): A Structural and Theoretical ExaminationOrganometallics, 15
-
R. Simons, P. Power (1996)
(η5-C5H5)(CO)2MoGeC6H3-2,6-Mes2: A Transition-Metal Germylyne ComplexJournal of the American Chemical Society, 118
-
R. Simons, L. Pu, M. Olmstead, P. Power (1997)
Synthesis and Characterization of the Monomeric Diaryls M{C6H3-2,6-Mes2}2 (M = Ge, Sn, or Pb; Mes = 2,4,6-Me3C6H2−) and Dimeric Aryl−Metal Chlorides [M(Cl){C6H3-2,6-Mes2}]2 (M = Ge or Sn)Organometallics, 16
- Datasource
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Abstract
Treatment of Ge(Cl)C6H3mes2-2,6 1 with1 equiv. of KC8 furnishes the new cyclotrigermenyl radical(GeC6H3mes2-2,6)3·, 2)which is characterized by EPR and X-ray crystallography; reduction with afurther equivalent of KC8 gives the new trigermenyl allyl anionanalogue K(GeC6H3mes2-2,6)3which has an open Ge3 framework with a wideGe–Ge–Ge angle of 159.19(10)°at the central Ge and aGe–Ge distance of 2.422(2) Å.
Journal
Chemical Communications – Royal Society of Chemistry
Published: Jan 1, 1997