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- Publisher
- Wiley
- Copyright
- Copyright © 2001 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
- ISSN
- 1040-0397
- eISSN
- 1521-4109
- DOI
- 10.1002/1521-4109(200111)13:17<1411::AID-ELAN1411>3.0.CO;2-G
- Publisher site
- See Article on Publisher Site
Abstract
The preparation and electrochemical characterization of glassy carbon, gold or carbon paste electrodes modified with 6,17‐Diferrocenyl‐dibenzo(b,i)5,9,14,18‐tetraaza(14)annulen)‐nickel(II) as well as their behavior as electrocatalysts toward the oxidation of nitric oxide is described. These modified electrodes were used for the development of amperometric sensors for the determination of nitric oxide in solution. The sensors were prepared by electrochemical deposition of the mentioned material on glassy carbon or gold electrodes or including it in a carbon paste electrode. The resulting sensors exhibited potent and persistent electrocatalytic activity towards the oxidation of nitric oxide with low detection limits (1 μM) and good linear relationship between the current and nitric oxide concentration.
Journal
Electroanalysis – Wiley
Published: Nov 1, 2001