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THE RATE OF SOLUTION OF SOLID SUBSTANCES IN THEIR OWN SOLUTIONS.

THE RATE OF SOLUTION OF SOLID SUBSTANCES IN THEIR OWN SOLUTIONS. 930 ARTHUR A. NOYES AND WILLIS R. WHITNEY Per cent. Chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21.77 Monochlor naphthol requires 19.66 per cent. ; dichlor naph- thol requires 33.02 per cent. There was evidently no simple substitution of C1 for NO,, and it was plain that more complica- ted changes than those involved by substitution had taken place. The inability to obtain a product offering the assurance of purity, caused a discontinuance of the work. The expulsion of the nitro group by chlorine under these conditions, is, how- ever, worthy of note. THE RATE OF SOLUTION OF SOLID SUBSTANCES IN THEIR OWN SOLUTIONS. BY ARTHCR A. NOYES AND WILLIS R WHITJEY Reiei5ed October ir, r89j S far as we know, the effect of the concentration on the rate A at which a solid substance dissolves in its own solution, has not heretofore been investigated. This is probably due to the experimental difficulties in the way of keeping the surface of the dissolving substance constant during the solution. The question is an http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of the American Chemical Society Unpaywall

THE RATE OF SOLUTION OF SOLID SUBSTANCES IN THEIR OWN SOLUTIONS.

Noyes, Arthur A.; Whitney, Willis R.
Journal of the American Chemical Society – Dec 1, 1897
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ISSN
0002-7863
DOI
10.1021/ja02086a003
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Abstract

930 ARTHUR A. NOYES AND WILLIS R. WHITNEY Per cent. Chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21.77 Monochlor naphthol requires 19.66 per cent. ; dichlor naph- thol requires 33.02 per cent. There was evidently no simple substitution of C1 for NO,, and it was plain that more complica- ted changes than those involved by substitution had taken place. The inability to obtain a product offering the assurance of purity, caused a discontinuance of the work. The expulsion of the nitro group by chlorine under these conditions, is, how- ever, worthy of note. THE RATE OF SOLUTION OF SOLID SUBSTANCES IN THEIR OWN SOLUTIONS. BY ARTHCR A. NOYES AND WILLIS R WHITJEY Reiei5ed October ir, r89j S far as we know, the effect of the concentration on the rate A at which a solid substance dissolves in its own solution, has not heretofore been investigated. This is probably due to the experimental difficulties in the way of keeping the surface of the dissolving substance constant during the solution. The question is an

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Journal of the American Chemical Society – Unpaywall

Published: Dec 1, 1897

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