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September, 1958] Renieratene, a New Carotenoid Containing Benzene Rings, 739 Isolated from a Sea Sponge Renieratene, a New Carotenoid Containing Benzene Rings, Isolated from a Sea Sponge* By Masaru YAMAGUCM (Received March 5, 1958) cluded that the R-group has the formula With regard to the chemical constitu- C9H11-, and that it contains one ring and tion of renieratenet), a carotenoid pigment three double bonds. Furthermore, it can isolated from a sponge "Reniera japonica", it has previously been shown from the be inferred from the analogy with another terminal group, that the ring may be a result of the chromic acid oxidation, by benzene ring. which crocetin dialdehyde has been iso- lated besides other products, that renie- ratene is a derivative of tetramethyl- octadeca-nonaene2). Shortly afterwards the author has elucidated the chemical constitution of isorenieratene (I), and it has become clear that isorenieral which is the degradation product of the former, has the constitution indicated by III). As isorenieral is also one of the degradation products of renieratene, it is clear that renieratene can be expressed by the partial formula III. Therefore the remaining problem in the chemical constitution of renieratene is the elucidation of R-group in the formula III.
Bulletin of the Chemical Society of Japan – Oxford University Press
Published: Apr 12, 2006
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