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Abstract
Reaction of a semi-rigid tripodal ligand 1,1′,1′′-(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tripyridinium-4-olate) (TTP) with Ln3+ (Ln = Eu, Gd) afforded rare (3,12)-connected metal–organic frameworks (MOFs). A topological simplification of such highly connected 3D MOFs on the basis of 2D CdI2 (3,6)-nets is proposed. The luminescent and anion exchange properties of the compounds were determined.
Journal
Chemical Communications – Royal Society of Chemistry
Published: Mar 22, 2011