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Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal... Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chemical Communications Royal Society of Chemistry

Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

Royal Society of Chemistry — Sep 20, 2011

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Royal Society of Chemistry
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Abstract

Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

Journal

Chemical CommunicationsRoyal Society of Chemistry

Published: Sep 20, 2011

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