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A Channel‐Free Soft‐Walled Capsular Calixarene Solid for Gas Adsorption

A Channel‐Free Soft‐Walled Capsular Calixarene Solid for Gas Adsorption A very good host: The crystalline capsular structure of para‐octanoylcalix(4)arene (see picture) is a promising adsorbent for saturated and unsaturated hydrocarbons, polarizable inert gases, and for carbon dioxide. The constant movement of acyl chains creates the effect of “soft cavity walls” in the calixarene capsule and allows gas adsorption even without permanent channels. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Angewandte Chemie International Edition Wiley

A Channel‐Free Soft‐Walled Capsular Calixarene Solid for Gas Adsorption

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References (44)

Publisher
Wiley
Copyright
Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1433-7851
eISSN
1521-3773
DOI
10.1002/anie.200800071
pmid
18567038
Publisher site
See Article on Publisher Site

Abstract

A very good host: The crystalline capsular structure of para‐octanoylcalix(4)arene (see picture) is a promising adsorbent for saturated and unsaturated hydrocarbons, polarizable inert gases, and for carbon dioxide. The constant movement of acyl chains creates the effect of “soft cavity walls” in the calixarene capsule and allows gas adsorption even without permanent channels.

Journal

Angewandte Chemie International EditionWiley

Published: Jul 14, 2008

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