Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/synthesis-of-ring-14-c-labelled-4-3-6-dimethyl-3-heptyl-phenol-UwxLiePNfk
References (9)
-
M. Ahel, W. Giger, M. Koch (1994)
Behaviour of alkylphenol polyethoxylate surfactants in the aquatic environment—I. Occurrence and transformation in sewage treatmentWater Research, 28
-
M. Ahel, W. Giger (1985)
Determination of alkylphenols and alkylphenol mono- and diethoxylates in environmental samples by high-performance liquid chromatographyAnalytical Chemistry, 57
-
S. Lussier, D. Champlin, J. LiVolsi, S. Poucher, R. Pruell (2000)
Acute toxicity of para‐nonylphenol to saltwater animalsEnvironmental Toxicology and Chemistry, 19
-
B. Bhatt, J. Prasad, G. Kalpana, S. Ali (1992)
Separation and Characterization of Isomers of p-Nonylphenols by Capillary GC/GC—MS/GC—FTIR TechniquesJournal of Chromatographic Science, 30
-
M. Bhatt, S. Kulkarni (1983)
Cleavage of EthersSynthesis, 1983
-
J. Press (1979)
Deethylation of Aryl Ethyl Ethers by Boron TribromideSynthetic Communications, 9
-
A. Meldahl, K. Nithipatikom, J. Lech (1996)
Metabolism of several 14C-nonylphenol isomers by rainbow trout (Oncorhynchus mykiss): in vivo and in vitro microsomal metabolites.Xenobiotica; the fate of foreign compounds in biological systems, 26 11
-
R. Ekelund, A. Bergman, Å. Granmo, M. Berggren (1990)
Bioaccumulation of 4-nonylphenol in marine animals--a re-evaluation.Environmental pollution, 64 2
-
M. Ahel, J. Mcevoy, W. Giger (1993)
Bioaccumulation of the lipophilic metabolites of nonionic surfactants in freshwater organisms.Environmental pollution, 79 3
- Publisher
- Wiley
- Copyright
- Copyright © 2001 John Wiley & Sons, Ltd.
- ISSN
- 0362-4803
- eISSN
- 1099-1344
- DOI
- 10.1002/jlcr.474
- Publisher site
- See Article on Publisher Site
Abstract
Ring‐14C‐labelled 4(3′‐, 6′‐, dimethyl‐3′‐,heptyl)‐phenol (NP), an isomer of paranonyl phenol was synthesized for use in aquatic toxicity and metabolism studies. A very efficient method involving alkylation of ring‐14C‐labelled anisole and tertiary alkyl bromide (3‐bromo‐3,6‐dimethyl heptane) with AlCl3 followed by cleavage of the resultant ether with BBr3 was used giving a 24% yield ring labelled 14C‐NP (specific activity: 16.205 MBq/mg and purity >95% by HPLC) after TLC separation. Copyright © 2001 John Wiley & Sons, Ltd.
Journal
Journal of Labelled Compounds and Radiopharmaceuticals – Wiley
Published: May 1, 2001