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Published information, both theoretical and experimental, on As chemical behavior in soils is reviewed. Because of many emission sources, As is ubiquitous. Thermodynamic calculations revealed that As(V) species (HAsO 4 2- >H2AsO 4 - at pH 7) are more abundant in soil solutions that are oxidized more than pe+pH>9. Arsenic is expected to be in As(III) form (HAsO 2 0 =H3AsO 3 0 >AsO 2 - =H2AsO 3 - at pH 7) in relatively anoxic soil solutions with pe+pH<7.
Water, Air, Soil Pollution – Springer Journals
Published: Apr 11, 2006
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