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Novel glass fabric-reinforced polybenzoxazine–silicate composites with polyvinyl butyral for high service temperature applications

Novel glass fabric-reinforced polybenzoxazine–silicate composites with polyvinyl butyral for high... The aim of this study is to develop novel glass fabric-reinforced polybenzoxazine–silicate composites with enhanced performances, which can overcome the disadvantages related to the low crosslink density of glass fabric-reinforced polybenzoxazine composites. Glass polybenzoxazine silicate composites were prepared via the copolymerization of bisphenol F benzoxazine using glass fabric, polyvinyl butyral as the coupling agent and various ratios of ethyl silicate. FTIR and DSC were utilized to study the chemical reactions and curing optimization, respectively. It was found that complete polymerization occurred at 200 °C. DMA analysis of the prepared glass polybenzoxazine silicate composites showed enhanced stiffness, crosslink density, service temperature, and network branching with uniform phase distribution. The thermal oxidative decomposition temperatures and char yield obtained by TGA and interfacial adhesion by SEM for glass polybenzoxazine silicate composites were found to be improved when compared to that of the glass polybenzoxazine composites. The composites prepared by this method showed enhanced service temperature, stiffness, crosslink density, thermal oxidative resistance, and char yield when compared to glass fabric-reinforced homopolymerized polybenzoxazine composites. These newly developed glass polybenzoxazine silicate composites are promising materials to overcome various shortcomings associated with polybenzoxazine and other traditional resin composites. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png NJC: New Journal of Chemistry Royal Society of Chemistry

Novel glass fabric-reinforced polybenzoxazine–silicate composites with polyvinyl butyral for high service temperature applications

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique
ISSN
1144-0546
eISSN
1369-9261
DOI
10.1039/c8nj02597e
Publisher site
See Article on Publisher Site

Abstract

The aim of this study is to develop novel glass fabric-reinforced polybenzoxazine–silicate composites with enhanced performances, which can overcome the disadvantages related to the low crosslink density of glass fabric-reinforced polybenzoxazine composites. Glass polybenzoxazine silicate composites were prepared via the copolymerization of bisphenol F benzoxazine using glass fabric, polyvinyl butyral as the coupling agent and various ratios of ethyl silicate. FTIR and DSC were utilized to study the chemical reactions and curing optimization, respectively. It was found that complete polymerization occurred at 200 °C. DMA analysis of the prepared glass polybenzoxazine silicate composites showed enhanced stiffness, crosslink density, service temperature, and network branching with uniform phase distribution. The thermal oxidative decomposition temperatures and char yield obtained by TGA and interfacial adhesion by SEM for glass polybenzoxazine silicate composites were found to be improved when compared to that of the glass polybenzoxazine composites. The composites prepared by this method showed enhanced service temperature, stiffness, crosslink density, thermal oxidative resistance, and char yield when compared to glass fabric-reinforced homopolymerized polybenzoxazine composites. These newly developed glass polybenzoxazine silicate composites are promising materials to overcome various shortcomings associated with polybenzoxazine and other traditional resin composites.

Journal

NJC: New Journal of Chemistry – Royal Society of Chemistry

Published: Sep 24, 2018

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