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Carbon Dioxide Reduction to Alcohols using Perovskite‐Type Electrocatalysts

Carbon Dioxide Reduction to Alcohols using Perovskite‐Type Electrocatalysts Electrochemical reduction of under ambient conditions to methanol, ethanol, and n‐propanol is reported at perovskite‐type electrocatalysts when incorporated into gas diffusion electrodes. In the absence of copper at the perovskite B lattice site, no activity was found. This investigation resulted in the identification of electrochemical conditions whereby perovskite‐type electrocatalysts could achieve cumulative Faradaic efficiencies for reduction to methanol, ethanol, and n‐propanol up to ≅40% at current densities of 180 mA/cm2. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of the Electrochemical Society IOP Publishing

Carbon Dioxide Reduction to Alcohols using Perovskite‐Type Electrocatalysts

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Copyright
Copyright © 1993 ECS - The Electrochemical Society
ISSN
0013-4651
eISSN
1945-7111
DOI
10.1149/1.2056131
Publisher site
See Article on Publisher Site

Abstract

Electrochemical reduction of under ambient conditions to methanol, ethanol, and n‐propanol is reported at perovskite‐type electrocatalysts when incorporated into gas diffusion electrodes. In the absence of copper at the perovskite B lattice site, no activity was found. This investigation resulted in the identification of electrochemical conditions whereby perovskite‐type electrocatalysts could achieve cumulative Faradaic efficiencies for reduction to methanol, ethanol, and n‐propanol up to ≅40% at current densities of 180 mA/cm2.

Journal

Journal of the Electrochemical Society – IOP Publishing

Published: Mar 1, 1993

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