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- Publisher
- Oxford University Press
- Copyright
- © 1991 The Chemical Society of Japan
- ISSN
- 0009-2673
- eISSN
- 1348-0634
- DOI
- 10.1246/bcsj.64.3538
- Publisher site
- See Article on Publisher Site
Abstract
Diperoxy esters having a benzophenone chromophore have been successfully synthesized from the reaction of 3-chloro-3-phenylphthalide (1) with 2,5-dihydroperoxy-2,5-dimethyl-3-hexyne (4a) or 2,5-dihydroperoxy-2,5-dimethylhexane (4b). The corresponding diperoxy esters had a UV absorption above 300 nm. The free radicals produced during the photolysis of these compounds initiated the radical polymerization of methyl methacrylate at room temperature under UV light.
Journal
Bulletin of the Chemical Society of Japan – Oxford University Press
Published: Jun 7, 2006