Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/self-assembly-of-oligo-p-phenylenevinylene-block-poly-ethylene-oxide-PlZZcmKSyj
References (41)
-
Hildegard Kukula, H. Schlaad, M. Antonietti, S. Förster (2002)
The formation of polymer vesicles or "peptosomes" by polybutadiene-block-poly(L-glutamate)s in dilute aqueous solution.Journal of the American Chemical Society, 124 8
-
S. Jenekhe, X. Chen (1999)
Self-assembly of ordered microporous materials from rod-coil block copolymersScience, 283 5400
-
J. and, W. Fann, P. Tsao, Kuen-Ru and, Shaw-An Chen (1999)
Fluorescence from Conjugated Polymer Aggregates in Dilute Poor SolutionJournal of Physical Chemistry A, 103
-
D. Marsitzky, T. Brand, Y. Geerts, M. Klapper, K. Müllen (1998)
Synthesis of rod-coil block copolymers via end-functionalized poly(p-phenylene)sMacromolecular Rapid Communications, 19
-
Wenjie Li, Todd Maddux, Luping Yu (1996)
Synthesis and Characterization of Diblock Copolymers Containing Oligothiophenes with Defined Regiospecificity and Molecular WeightsMacromolecules, 29
-
P. Dalhaimer, F. Bates, D. Discher (2003)
Single Molecule Visualization of Stable, Stiffness-Tunable, Flow-Conforming Worm MicellesMacromolecules, 36
-
E. Peeters, A. Ramos, Scj Meskers, R. Janssen (2000)
Singlet and triplet excitations of chiral dialkoxy-p-phenylene vinylene oligomersJournal of Chemical Physics, 112
-
Y. Yi, X. Wan, Xinghe Fan, Rong Dong, Qifeng Zhou (2003)
Synthesis of a Novel Hybrid Liquid-Crystalline Rod-Coil Diblock CopolymerJournal of Polymer Science Part A, 41
-
Hengbin Wang, Hsien‐Hau Wang, V. Urban, K. Littrell, P. Thiyagarajan, Luping Yu (2000)
Syntheses of Amphiphilic Diblock Copolymers Containing a Conjugated Block and Their Self-Assembling PropertiesJournal of the American Chemical Society, 122
-
David Williams, G. Fredrickson (1992)
Cylindrical micelles in rigid-flexible diblock copolymersMacromolecules, 25
-
H. Kretzschmann, H. Meier (1991)
A new synthesis of soluble poly(1,4-phenylenevinylene)s and poly(2,5-pyrimidinylenevinylene)sTetrahedron Letters, 32
-
E. Zubarev, M. Pralle, Eli Sone, S. Stupp (2001)
Self-assembly of dendron rodcoil molecules into nanoribbons.Journal of the American Chemical Society, 123 17
-
R. Liggins, H. Burt (2002)
Polyether-polyester diblock copolymers for the preparation of paclitaxel loaded polymeric micelle formulations.Advanced drug delivery reviews, 54 2
-
Wenjie Li, Henbin Wang, Luping Yu, T. Morkved, Henrich Jaeger (1999)
Syntheses of Oligophenylenevinylenes-Polyisoprene Diblock Copolymers and Their Microphase SeparationMacromolecules, 32
-
Annette Rösler, Guido Vandermeulen, H. Klok (2001)
Advanced drug delivery devices via self-assembly of amphiphilic block copolymers.Advanced drug delivery reviews, 53 1
-
S. Chen, A. Su, S. Han, S. Chen, Y. Lee (2004)
Molecular Aggregation and Luminescence Properties of Bulk Poly(2,5-di-n-octyloxy-1,4-phenylenevinylene)Macromolecules, 37
-
Ji-Woong and, E. Thomas (2004)
Anisotropic Micellar Nanoobjects from Reactive Liquid Crystalline Rod−Coil Diblock CopolymersMacromolecules, 37
-
Myongsoo Lee, B. Cho, W. Zin (2001)
Supramolecular structures from rod-coil block copolymers.Chemical reviews, 101 12
-
J. Kallitsis, A. Andreopoulou (2003)
Processable photonic polymers with controllable propertiesJournal of Polymer Science Part B, 41
-
John Chen, E. Thomas, C. Ober, S. Hwang (1995)
Zigzag Morphology of a Poly(styrene-b-hexyl isocyanate) Rod-Coil Block CopolymerMacromolecules, 28
-
Y. Yamamoto, Y. Nagasaki, Masao Kato, K. Kataoka (1999)
Surface charge modulation of poly(ethylene glycol)-poly(D,L-lactide) block copolymer micelles: Conjugation of charged peptidesColloids and Surfaces B: Biointerfaces, 16
-
U. Stalmach, Bert Boer, A. Post, P. Hutten, G. Hadziioannou (2001)
Synthesis of a Conjugated Macromolecular Initiator for Nitroxide-Mediated Free Radical Polymerization.Angewandte Chemie, 40 2
-
Hengbin Wang, W. You, P. Jiang, Luping Yu, H. Wang (2004)
Supramolecular self-assembly of conjugated diblock copolymers.Chemistry, 10 4
-
P. Gopalan, Xuefa Li, Mingqi Li, C. Ober, C. Gonzales, C. Hawker (2003)
Rod–coil block copolymers: An iterative synthetic approach via living free‐radical proceduresJournal of Polymer Science Part A, 41
-
T. Khan, R. Mobbs, C. Price, J. Quintana, R. Stubbersfield (1987)
Synthesis and colloidal behaviour of a polystyrene-b-poly(ethylene oxide) block copolymerEuropean Polymer Journal, 23
-
S. Lecommandoux, M. Achard, Josef Langenwalter, H. Klok (2001)
Self-Assembly of Rod−Coil Diblock Oligomers Based on α-Helical PeptidesMacromolecules, 34
-
Viola Francke, H. Räder, Y. Geerts, K. Müllen (1998)
Synthesis and characterization of a poly(para-phenyleneethynylene)-block-poly(ethylene oxide) rod-coil block copolymerMacromolecular Rapid Communications, 19
-
A. Rieche, H. Gross, E. Höft (1960)
Über α‐Halogenäther, IV. Synthesen aromatischer Aldehyde mit Dichlormethyl‐alkyläthernChemische Berichte, 93
-
Y. Tu, X. Wan, Dong Zhang, and Zhou, Chi Wu (2000)
Self-Assembled Nanostructure of a Novel Coil−Rod Diblock Copolymer in Dilute SolutionJournal of the American Chemical Society, 122
-
J. Ryu, Nam-Keun Oh, W. Zin, Myongsoo Lee (2004)
Self-assembly of rod-coil molecules into molecular length-dependent organization.Journal of the American Chemical Society, 126 11
-
P. Leclère, E. Hennebicq, A. Calderone, P. Brocorens, A. Grimsdale, K. Müllen, J. Brédas, R. Lazzaroni (2003)
Supramolecular organization in block copolymers containing a conjugated segment: a joint AFM/molecular modeling studyProgress in Polymer Science, 28
-
T. Kurihara, Y. Mori, T. Kaino, H. Murata, N. Takada, T. Tsutsui, S. Saitō (1991)
Spectra of χ(3) (−3ω; ω, ω, ω) in poly(2,5-dimethoxy p-phenylene vinylene) (MO-PPV) for various conversion levelsChemical Physics Letters, 183
-
J. Burroughes, D. Bradley, A. Brown, R. Marks, K. Mackay, R. Friend, P. Burns, A. Holmes (1990)
Light-emitting diodes based on conjugated polymersNature, 347
-
K. Loos, S. Muñoz‐Guerra (2000)
Supramolecular Polymers -
Lifeng Zhang, A. Eisenberg (1999)
Crew-cut aggregates from self-assembly of blends of polystyrene-b-poly(acrylic acid) block copolymers and homopolystyrene in solutionJournal of Polymer Science Part B, 37
-
R. Lenz, Chien-Chung Han, M. Lux (1989)
HIGHLY CONDUCTING, IODINE-DOPED ARYLENE VINYLENE COPOLYMERS WITH DIALKOXYPHENYLENE UNITSPolymer, 30
-
B. Gallot (1996)
Comb-like and block liquid crystalline polymers for biological applicationsProgress in Polymer Science, 21
-
Erik Hagberg, B. Goodridge, O. Ugurlu, S. Chumbley, V. Sheares (2004)
Development of a Versatile Methodology for the Synthesis of Poly(2,5-benzophenone) Containing Coil−Rod−Coil Triblock CopolymersMacromolecules, 37
-
P. Leclère, A. Calderone, D. Marsitzky, V. Francke, Y. Geerts, K. Müllen, J. Brédas, R. Lazzaroni (2000)
Highly Regular Organization of Conjugated Polymer Chains via Block Copolymer Self-AssemblyAdvanced Materials, 12
-
H. Kretzschmann, H. Meier (1994)
2,5‐Dialkoxysubstituierte Oligo‐ und Poly(1,4‐phenylenethenylen)eJournal Fur Praktische Chemie-chemiker-zeitung, 336
-
Jinsong Liu, E. Sheina, T. Kowalewski, R. Mccullough (2002)
Tuning the electrical conductivity and self-assembly of regioregular polythiophene by block copolymerization: nanowire morphologies in new di- and triblock copolymers.Angewandte Chemie, 41 2
- Publisher
- Wiley
- Copyright
- Copyright © 2005 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 0887-624X
- eISSN
- 1099-0518
- DOI
- 10.1002/pola.20631
- Publisher site
- See Article on Publisher Site
Abstract
Rod–coil amphiphilic diblock copolymers, consisting of oligo(p‐phenylenevinylene) (OPV) as a rod and hydrophobic block and poly(ethylene oxide) (PEO) as a coil and hydrophilic block, were synthesized by a convergent method. The aggregation behavior of the block copolymers in a selective solvent (tetrahydrofuran/H2O) was probed with the absorption and emission of the OPV block. With increasing H2O concentration, the absorption maximum was blueshifted, the emission from the molecularly dissolved OPV decreased, and that from the aggregated OPV increased. This indicated that the OPV blocks formed H‐type aggregates in which the OPV blocks aligned in a parallel orientation with one another. The transmission electron microscopy observation revealed that the block copolymers with PEO weight fractions of 41 and 62 wt % formed cylindrical aggregates with a diameter of 6–8 nm and a length of several hundreds nanometers, whereas the block copolymer with 79 wt % PEO formed distorted spherical aggregates with an average diameter of 13 nm. Furthermore, the solubilization of an OPV homooligomer with the block copolymer was studied. When the total polymer concentration was less than 0.1 wt %, the block copolymer solubilized OPV with a 50 mol % concentration. The structure of the aggregates was a cylinder with a relatively large diameter distribution. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1569–1578, 2005
Journal
Journal of Polymer Science Part A Polymer Chemistry – Wiley
Published: Mar 15, 2006
Keywords: ; ; ; ;