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A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives

A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High... Sensors and sensitivity: A highly luminescent microporous metal–organic framework, (Zn2(bpdc)2(bpee)) (bpdc=4,4′‐biphenyldicarboxylate; bpee=1,2‐bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4‐dinitrotoluene and the plastic explosive taggant 2,3‐dimethyl‐2,3‐dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Angewandte Chemie International Edition Wiley

A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives

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References (42)

Publisher
Wiley
Copyright
Copyright © 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1433-7851
eISSN
1521-3773
DOI
10.1002/anie.200804853
pmid
19180622
Publisher site
See Article on Publisher Site

Abstract

Sensors and sensitivity: A highly luminescent microporous metal–organic framework, (Zn2(bpdc)2(bpee)) (bpdc=4,4′‐biphenyldicarboxylate; bpee=1,2‐bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4‐dinitrotoluene and the plastic explosive taggant 2,3‐dimethyl‐2,3‐dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra).

Journal

Angewandte Chemie International EditionWiley

Published: Mar 16, 2009

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