Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/oxford-university-press/phase-transitions-and-thermodynamic-properties-of-rubidium-and-cesium-MTeF5f9afH
References (5)
-
K. Pitzer, W. Gwinn (1942)
Energy Levels and Thermodynamic Functions for Molecules with Internal Rotation I. Rigid Frame with Attached TopsJournal of Chemical Physics, 10
-
G. Parry (1962)
Studies in domain crystallography. I. The composite reciprocal lattice of a multidomain (`hybrid') crystalActa Crystallographica, 15
-
T. Matsuo, H. Suga, S. Seki (1968)
Thermodynamic Properties and Phase Transitions of Sodium Cyanide CrystalBulletin of the Chemical Society of Japan, 41
-
H. Suga, T. Matsuo, S. Seki (1965)
Thermodynamic Properties and Order-Disorder Phase Transitions of the Potassium Cyanide CrystalBulletin of the Chemical Society of Japan, 38
-
G. Parry (1962)
Studies in domain crystallography. II. A new low‐temperature crystal structure of potassium cyanideActa Crystallographica, 15
- Publisher
- Oxford University Press
- Copyright
- © 1968 The Chemical Society of Japan
- ISSN
- 0009-2673
- eISSN
- 1348-0634
- DOI
- 10.1246/bcsj.41.1747
- Publisher site
- See Article on Publisher Site
Abstract
Heat-capacity measurements were performed for rubidium and cesium cyanide crystals between 15 and 300°K. It is found that each crystal has only one anomalous peak in its heat capacity curve, being located at 110.3°K and 193.1°K for rubidium and cesium cyanides, respectively. By the comparison of the present data with those for potassium and sodium cyanides, it was shown that these anomalous heat capacities can be interpreted in terms of the orientational ordering processes of cyanide ions in the crystals. It was suggested that there should exist the residual entropy due to the frozen-in state in their orientational configuration and they were estimated as Rln4 for rubidium cyanide and Rln2 for cesium cyanide.
Journal
Bulletin of the Chemical Society of Japan – Oxford University Press
Published: Mar 27, 2006