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References (6)
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H. Nielsen (1951)
The Vibration-Rotation Energies of MoleculesReviews of Modern Physics, 23
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Y. Morino, C. Matsumura (1967)
Microwave Spectra and Equilibrium Structure of Carbonyl SulfideBulletin of the Chemical Society of Japan, 40
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M. Strandberg, T. Wentink, A. Hill (1949)
The Microwave Spectrum of Carbonyl SelenidePhysical Review, 75
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W. Low (1955)
Fermi Resonance in the Microwave Spectrum of LinearXYZMoleculesPhysical Review, 97
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T. Wentink (1959)
Triatomic Linear Molecules Containing Carbon and Oxygen, Sulfur, Selenium, or Tellurium. II. Potential ConstantsJournal of Chemical Physics, 30
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Y. Morino, E. Hirota (1958)
The Centrifugal Distortion and the l-Type Doubling Constants in Linear XYZ-Type Molecules. The Determination of Force Field by These ConstantsBulletin of the Chemical Society of Japan, 31
- Publisher
- Oxford University Press
- Copyright
- © 1967 The Chemical Society of Japan
- ISSN
- 0009-2673
- eISSN
- 1348-0634
- DOI
- 10.1246/bcsj.40.1101
- Publisher site
- See Article on Publisher Site
Abstract
The microwave spectra of the OCSe molecule have been measured for the ground and vibrationally excited states of a number of isotopic species under the natural abundance ratio. It was concluded from the results that the rs-structure is given by r(O–C)=1.157 Å and rs(C–Se)=1.708 Å, and that the general quadratic force field is represented by fR(CSe)=5.42, fr(CO)=15.38, fRr=0.68, and fα=0.286 md/Å.
Journal
Bulletin of the Chemical Society of Japan – Oxford University Press
Published: Mar 27, 2006