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A Facile Route to Steroidal 6-Deoxy-α-L-allopyranosides

A Facile Route to Steroidal 6-Deoxy-α-L-allopyranosides Abstract The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cis-diol via an intermediate bromohydrin. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Synthetic Communications Taylor & Francis

A Facile Route to Steroidal 6-Deoxy-α-L-allopyranosides

13 pages

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References (16)

Publisher
Taylor & Francis
Copyright
Copyright Taylor & Francis Group, LLC
ISSN
1532-2432
eISSN
0039-7911
DOI
10.1080/00397919808004442
Publisher site
See Article on Publisher Site

Abstract

Abstract The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cis-diol via an intermediate bromohydrin.

Journal

Synthetic CommunicationsTaylor & Francis

Published: Sep 1, 1998

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