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From discrete [Y(DMF)8][Cu4(µ3-I)2(µ-I)3I2] ion pairs to extended [Y(DMF)6(H2O)2][Cu7(µ4-I)3(µ3-I)2(µ-I)4(I)]1∞ and [Y(DMF)6(H2O)3][CuI7CuII2(µ3-I)8(µ-I)6]2∞ arrays by H-bond templating in a confined solvent-free environment

From discrete [Y(DMF)8][Cu4(µ3-I)2(µ-I)3I2] ion pairs to extended... An ionic heterometallic species [Y(DMF)][Cu(µ-I)(µ-I)I]() was isolated from a solution of CuI, NHI and YI(PrOH) in DMF–isopropoxyethanol, and was converted in a confined environment by progressive substitution of the DMF ligands with water molecules first into a 1D zig-zag structure [Y(DMF)(HO)][Cu(µ-I)(µ-I)(µ-I)(I)]() and finally into a 2D sheet [Y(DMF)(HO)][CuCu(µ-I)(µ-I)]() by H-bond templating. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Dalton Transactions Royal Society of Chemistry

From discrete [Y(DMF)8][Cu4(µ3-I)2(µ-I)3I2] ion pairs to extended [Y(DMF)6(H2O)2][Cu7(µ4-I)3(µ3-I)2(µ-I)4(I)]1∞ and [Y(DMF)6(H2O)3][CuI7CuII2(µ3-I)8(µ-I)6]2∞ arrays by H-bond templating in a confined solvent-free environment

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
1477-9226
eISSN
1477-9234
DOI
10.1039/b616800k
pmid
17213924
Publisher site
See Article on Publisher Site

Abstract

An ionic heterometallic species [Y(DMF)][Cu(µ-I)(µ-I)I]() was isolated from a solution of CuI, NHI and YI(PrOH) in DMF–isopropoxyethanol, and was converted in a confined environment by progressive substitution of the DMF ligands with water molecules first into a 1D zig-zag structure [Y(DMF)(HO)][Cu(µ-I)(µ-I)(µ-I)(I)]() and finally into a 2D sheet [Y(DMF)(HO)][CuCu(µ-I)(µ-I)]() by H-bond templating.

Journal

Dalton Transactions – Royal Society of Chemistry

Published: Jan 9, 2007

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