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Chemical removal of nitrate from water

Chemical removal of nitrate from water HIGH levels of nitrate in ground water can pose a serious health risk. Reduction of nitrate to nitrite in the gut may cause methemoglobinaemia1both in newborn infants and in adults deficient in glucose-phosphate dehydrogenase2. Under abnormal circumstances, reduction to nitrite can also occur in the stomach to form N-nitrosamines, a postulated cause of stomach cancer3. Nitrate outflow onto shallow continental shelves can promote nearshore algal blooms. Both natural and anthropogenic sources contribute to nitrate pollution. In the United States4 and Europe5, legislation now specifies a maximum permissible nitrate level in drinking water. Techniques such as selective ion exchange6, reverse osmosis, electrodialysis and distillation exist to transfer nitrate between two bodies of water, but only biological processes are presently available for nitrate destruction. Here I describe a chemical process in which aluminium powder reduces nitrate to ammonia, nitrogen and nitrite. In a pH range of 9 to 10.5, selective reduction of nitrate relative to sulphate is possible, and between pH 9.1 and 9.3, loss of the reductant through decomposition of water can be minimized to less than 2%. Subsequent control of pH and concentrations of dissolved aluminium, nitrite and ammonia should be possible at a realistic cost, making this process potentially useful for combating nitrate pollution. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Nature Springer Journals

Chemical removal of nitrate from water

Murphy, Andrew P.
Nature , Volume 350 (6315) – Mar 21, 1991
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References (7)

Publisher
Springer Journals
Copyright
Copyright © 1991 by Nature Publishing Group
Subject
Science, Humanities and Social Sciences, multidisciplinary; Science, Humanities and Social Sciences, multidisciplinary; Science, multidisciplinary
ISSN
0028-0836
eISSN
1476-4687
DOI
10.1038/350223a0
Publisher site
See Article on Publisher Site

Abstract

HIGH levels of nitrate in ground water can pose a serious health risk. Reduction of nitrate to nitrite in the gut may cause methemoglobinaemia1both in newborn infants and in adults deficient in glucose-phosphate dehydrogenase2. Under abnormal circumstances, reduction to nitrite can also occur in the stomach to form N-nitrosamines, a postulated cause of stomach cancer3. Nitrate outflow onto shallow continental shelves can promote nearshore algal blooms. Both natural and anthropogenic sources contribute to nitrate pollution. In the United States4 and Europe5, legislation now specifies a maximum permissible nitrate level in drinking water. Techniques such as selective ion exchange6, reverse osmosis, electrodialysis and distillation exist to transfer nitrate between two bodies of water, but only biological processes are presently available for nitrate destruction. Here I describe a chemical process in which aluminium powder reduces nitrate to ammonia, nitrogen and nitrite. In a pH range of 9 to 10.5, selective reduction of nitrate relative to sulphate is possible, and between pH 9.1 and 9.3, loss of the reductant through decomposition of water can be minimized to less than 2%. Subsequent control of pH and concentrations of dissolved aluminium, nitrite and ammonia should be possible at a realistic cost, making this process potentially useful for combating nitrate pollution.

Journal

Nature – Springer Journals

Published: Mar 21, 1991

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