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- Publisher
- Wiley
- Copyright
- Copyright © 2010 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 0108-2701
- eISSN
- 2053-2296
- DOI
- 10.1107/S010827011003578X
- pmid
- 20921605
- Publisher site
- See Article on Publisher Site
Abstract
The new high‐spin iron(II) complex, [Fe(C12H10N6)2(H2O)2](C8H3N4S)2 or [Fe(abpt)2(H2O)2](tcnsme)2 [where abpt is 4‐amino‐3,5‐di‐2‐pyridyl‐4H‐1,2,4‐triazole and tcnsme is the 1,1,3,3‐tetracyano‐2‐methylthiopropenide anion], consists of discrete [Fe(abpt)2(H2O)2]2+ dications, where the FeII ion is coordinated by two N,N′‐bidentate chelating abpt ligands in the equatorial plane and two water molecules in trans positions, generating a distorted octahedral [FeN4O2] environment. The cationic unit is neutralized by two polynitrile tcnsme anions, in which the C—N, C—C and C—S bond lengths indicate extensive electronic delocalization. In the crystal structure, the dications and anions are linked through O—H...N and N—H...N hydrogen bonds involving the water H atoms and those of the NH2 groups and the N atoms of the CN groups, leading to the formation of a three‐dimensional network.
Journal
Acta Crystallographica Section C Crystal Structure Communications – Wiley
Published: Mar 15, 2011