Environmental Technology

Zhang, Xu; Zhang, Shuqin; Liu, Shuang; Ren, Dajun; Zhang, Xiaoqing

doi: 10.1080/09593330.2023.2283061pmid: 37947180

With the increasing shortage of land resources and the aggravation of soil pollution in mining areas, the remediation of soil in abandoned mining areas has gradually attracted people's attention. The remediation of heavy metal contaminated soil in mining areas is the key to reduce the harm of heavy metals to the environment and human health. In this study, municipal sludge and phytoremediation technology were combined to investigate the migration and transformation of heavy metals at the soil-plant interface in improved mining areas through indoor pot experiments. The results showed that heavy metals in non-rhizosphere soil entered the rhizosphere environment with the growth of plants, leading to the increase of heavy metal content in rhizosphere soil. The cumulative amounts of Cu, Zn, Pb and Cd were 1299.32, 832.10, 347.89 and 71.34 mg/kg, respectively. The content of oxidized Cu and Zn decreased with increasing planting days, while the oxidized Pb and Cd showed an increasing trend. Under acidic conditions, H+ is easy to compete with heavy metal ions for exchangeable positions in the clay mineral layer, so that the reducible heavy metals are easy to be converted into exchangeable states. In this paper, the effects of various factors on the distribution of heavy metals were discussed by adjusting soil pH, adding humic acid and root exudates, so as to analyse the migration and transformation mechanism of heavy metals at the soil-plant interface, and provide a reliable theoretical basis for soil remediation in mining areas.

Wang, Wenfan; Zhao, Zhuoqun; Yang, Jian; Lian, Xiaojian; Xie, Xiaojie; Chen, Hengyuan; Wang, Min; Zheng, Huabao

doi: 10.1080/09593330.2023.2283064pmid: 37953714

This work aims to investigate the effective removal of oil in food waste (FW). Two bacteria, Bacillus subtilis and Bacillus glycinifermentans, were obtained under high temperature conditions and named YZQ-2 and YZQ-5, respectively. The oil degradation rate of two bacteria was explored under different pH value, temperature, and NaCl concentration. In addition, the lipase and emulsifying activity were evaluated. The maximum oil degradation rate was 83.41 ± 0.86% and the maximum lipase activity reached 89.73 ± 20.89 U L-1 with YZQ-2. The fermentation broth of YZQ-2 displayed exceptional emulsification activity. Subsequently, YZQ-2 and YZQ-5 were added to aerobic FW composting. The moisture content of the compost treated with inoculated strains decreased at a faster rate during the first three days of composting. The microbial quantity increased rapidly in the first three days, and the oil degradation rate reached 39.96% after five days. Due to the excellent adaptability to high temperature and ability to degrade oil, strains YZQ-2 and YZQ-5 exhibit superior potential for various applications.

Xiang, Xiaofang; Jiang, Wen; Liu, Zhenzhong

doi: 10.1080/09593330.2023.2283071pmid: 38350024

Nanoplastics (NPs) are usually formed by the decomposition of large plastics, which will cause water pollution after entering the water body. Carbon filter column is used to adsorb and remove polystyrene nanoparticles (PSNPs). The influence of experimental conditions on adsorption was investigated and fitted by kinetic model. The results show that increasing the height of carbon filter column and decreasing the initial concentration of PSNPs and water flow rate can prolong the breakthrough time of carbon filter column. When the initial concentration of PSNPs is 0.8 mg L−1, the influent flow rate is 4 mL min−1 and the height of carbon filter bed is 8.5 cm, the removal effect is the best, and the depletion point of carbon filter column is extended to 48 h. Adams-Bohart model is suitable for describing the initial stage of adsorption. Thomas and Yoon-Nelson models can well describe the whole dynamic adsorption process of PSNPs, and Yoon-Nelson model can accurately predict the time required for 50% PSNPs to penetrate the carbon column. The adsorption mechanism of NPs by carbon filter column is mainly through the attachment sites and pore retention provided by particles on the surface of activated carbon. This study can provide new technical and theoretical support for the removal of NPs.

Wang, Xueshun; Li, Hongyu; Zhang, Shuang; Gao, Fengwen; Sun, Xue; Ren, Xuekun

doi: 10.1080/09593330.2023.2283073pmid: 37953712

Cadmium (Cd) pollution is a serious threat to food safety and human health. Minimization of Cd uptake and enhancing Cd tolerance in plants are vital to improve crop yield and reduce hazardous effects to humans. In this study, we investigate the effect of a synergistic system with phytohormone (24-Epibrassinolide, EBL) and silicon (Si) on Cd toxicity and accumulation of rice plants. The results revealed that Si, EBL and their combination rescued Cd-induced growth inhibition, as evidenced by the increased dry weight of root and shoot. The chlorophyll content and photosynthetic performance were improved. The activity of antioxidant enzymes (SOD, POD and CAT) was increased and oxidative stress was alleviated. More importantly, Cd content in root was decreased by 20.25%, 17.72% and 27.84%, while Cd content in shoot decreased by 21.17%, 16.47% and 25.88%, respectively. Moreover, Si, EBL and Si + EBL treatment enriched cell wall-bound Cd and reduced Cd toxicity to functional organelles. Meanwhile, the residual form of Cd was enriched and the highly toxic forms of Cd (inorganic and water-soluble Cd) were decreased. The joint application showed better effects than applying Si and EBL alone. Collectively, this study provides an effective way for Cd toxicity mitigation in rice plants.

Zhu, Wenxin; Liu, Leping; Lao, YuanXia; He, Yan

doi: 10.1080/09593330.2023.2283082pmid: 37947794

Methylene blue (MB) is a prevalent pollutant in organic wastewater. For this research, eucalyptus wood was used as a template, into which quartz powder dissolved in NaOH was grown, resulting in a low-cost and efficient porous silica adsorbent material (PSAM). This PSAM successfully replaces expensive materials for MB removal from water. Through the application of Scanning Electron Microscopy (SEM) and Brunauer–Emmett–Teller (BET) analysis, it became evident that PSAM displays a porous slit pore structure characterized by numerous active sites, leading to an impressive maximum specific surface area of 88.05 m²/g. The central objective of this research was to investigate the impact of experimental temperature, initial dye concentration, and pH on the adsorption process. The adsorption kinetics were analyzed using the pseudo-first-order and pseudo-second-order models, as well as the Langmuir model. Remarkably, PSAM exhibited a substantial maximum adsorption capacity of 90.01 mg/g at 293 K, achieving an adsorption rate of over 85% within a mere 10-minute timeframe. The thermodynamic analysis revealed that the adsorption of MB onto PSAM was characterized by spontaneity and accompanied by heat absorption. Fourier Transform Infrared (FTIR) and SEM comparisons of PSAM before and after adsorption indicated that MB adsorption primarily occurred through electrostatic gravitational binding. In comparison to other adsorbents, PSAM exhibited exceptional efficacy in removing MB from water.

Coelho, Leticya Lais; Vieira, Jamile dos Santos; Hissanaga, Adriano Martins; Rosseti, Marcel; Wilhelm, Michaela; Hotza, Dachamir; de and Fátima Peralta Muniz Moreira, Regina

doi: 10.1080/09593330.2023.2283084pmid: 37948153

Photocatalytic membranes (PM) have been investigated as an antifouling strategy for membrane separation processes. Coating ceramic membranes with photocatalytic layers can provide a highly active surface capable of degrading foulants and smaller molecules improving the membrane’s performance when the surface is irradiated by a suitable light. Nevertheless, the coating process often leads to pore blockage due to the formation or deposition of thick layers of photocatalyst on membrane surfaces, which modifies the original membranes’ average pore size and reduces membrane permeability. A facile sol-gel dip coating process was used to produce PM without modifying the original surface morphology of alumina microfiltration membranes. A 3.7-fold increase in permeate volume after 90 min of permeation of an acetaminophen solution in continuous filtration mode under UV light (λ = 365 nm LED, 10W) using titania as photocatalyst compared to the bare alumina membrane without irradiation. Furthermore, fouling modelling proved a reduction in the fouling constant, while fouling mechanisms were not modified. Raman analysis showed 100% anatase formed on the membrane surface. Although membranes could remove up to 87% TOC for oily wastewater filtration, antifouling capabilities for this type of effluent were not observed for the photocatalytic membranes mainly due to fouling inside the pores and light attenuation due to the thick fouling layer on the membrane surface.

Shen, Zhenyu; Zhu, Zhexin; Wang, Gangqiang; Miao, Yongquan; Lu, Wangyang

doi: 10.1080/09593330.2023.2283085pmid: 38037354

In this study, the porous graphite phase carbon nitride photocatalyst (P-g-C3N4) is prepared by the CaCO3 template method, and then P-g-C3N4/T-polyethylene terephthalate (T-PET) catalytic fibre is prepared by the padding method. P-g-C3N4 can provide more active sites than g-C3N4 as proved by the Brunauer–Emmett–Teller and the UV–Visible diffuse reflectance test. P-g-C3N4 powder catalyst successfully supports PET fibre as proved by scanning electron microscope, Fourier infrared spectroscopy and X-ray diffraction spectroscopy. The photocatalytic performance of P-g-C3N4/T-PET catalytic fibre is tested by constructing a single hexavalent chromium or hexavalent chromium/organic pollutant binary pollution system. The potential application value of P-g-C3N4/T-PET catalytic fibre is further explored by simulating the complex actual water environment. After five recycles, P-g-C3N4/T-PET catalytic fibre shows good catalytic performance. The mechanism of P-g-C3N4/PET photocatalytic degradation of organic pollutants is proposed through the capture agent experiment and electron paramagnetic resonance spectroscopy. Among them, •O2 − is the most important active species of P-g-C3N4 catalytic fibre, which is used for the oxidation of organic pollutants. At the same time, photoelectrons generated by the catalytic fibre are used to reduce hexavalent chromium. The efficiency of P-g-C3N4 to remove pollutants is improved by using PET fibre as a carrier, which not only solves the problem of difficult recovery of powder catalysts but also provides more active sites.

Pang, Yuwan; Zhen, Feng; Wang, Dehan; Luo, Zifeng; Huang, Jianfeng; Zhang, Yanli

doi: 10.1080/09593330.2023.2283086pmid: 37970824

Aim: Chicken manure is known to produce strong odors during aerobic composting, which not only pollutes the surrounding environment but also leads to the loss of valuable nutrients like nitrogen and sulfur, thus reducing the quality of the fertilizer. Methods: In this study, we explored the use of biochar combined with MgO desulfurization waste residue (MDWR) as a novel composting additive. Our approach involved conducting composting tests, characterizing the compost samples, conducting pot experiments, and examining the impact of the additives on nitrogen retention, deodorization, and compost quality. Results: Our findings revealed that the addition of biochar and MDWR significantly reduced ammonia volatilization in chicken manure compost, demonstrating a reduction rate of up to 60.12%. Additionally, the emission of volatile organic compounds (VOCs) from chicken manure compost treated with biochar and MDWR decreased by 44.63% compared to the control group. Conclusions: The composting product treated with both biochar and MDWR (CMB) exhibited a 67.7% increase in total nitrogen (TN) compared to the blank control group, surpassing the other treatment groups and showcasing the synergistic effect of these two additives on nitrogen retention. Moreover, the CMB treatment facilitated the formation of struvite crystals. Furthermore, our pot experiment results demonstrated that the CMB treatment enhanced vegetable yield and quality while reducing nitrate content. These findings highlight the significant impact of MDWR on nitrogen retention, deodorization, and compost quality enhancement, thereby indicating its promising application prospects.

Li, Zhenghao; Cheng, Yuanyuan; Zeng, Mingjing; Luo, Yi; Hou, Yiran; Wu, Junfeng; Nie, Jiale; Long, Bei

doi: 10.1080/09593330.2023.2283087pmid: 38008972

This study elucidates the impact of fluctuating influent conditions and in situ ultrasonic wave exposure on the stability of aerobic granular sludge (AGS) in the treatment of simulated wastewater emanating from rare earth mining operations. During a stable influent period spanning from Day 1 to Day 95, the seed granules underwent an initial disintegration followed by a re-granulation phase. The secondary granulation was achieved on Day 80 and Day 40 for the ultrasonic reactor (R1) and the control reactor (R2), respectively. Notably, granules formed in R1 exhibited a more porous structure compared to those generated in R2. Subsequently, when the ammonia nitrogen in the influent oscillated between 100 and 500 mg/L during Days 96-140, both reactors yielded compact and densely structured granules. Nitrogen removal profiles were comparable between the two reactors: the removal efficiencies for ammonia nitrogen and total inorganic nitrogen escalated from 95% and 80%, respectively, during Days 1-95, to 95% and 90%, respectively, post-Day 140. A suite of performance metrics indicated that steady-state granules from R1 outperformed those from R2 across several parameters. Specifically, the nitrification/denitrification rates, and relative abundance of denitrifying bacteria were all higher in granules from R1. Conversely, the relative abundance of nitrifying bacteria was comparable between granules from both reactors. However, R1 granules demonstrated lower sludge concentration and smaller average particle size than their R2 counterparts. In conclusion, the AGS system demonstrated robust resilience to fluctuating ammonia nitrogen, and the application of ultrasonic waves significantly enhanced granular activity while achieving in situ sludge reduction.

Zhang, Qiming; Tang, Tian; Cui, Guodong; Wang, Zheng; Liu, Yangsheng

doi: 10.1080/09593330.2023.2283090pmid: 37970842

Sewage sludge requires effective dewatering and high nutrients retention before disposal for agricultural application. Pressurized electro-osmotic dewatering (PEOD) process with low energy consumption can effectively remove water from sludge, but the influences of PEOD process on nutrients for agricultural application still lacks in-depth research. In this study, the influences of PEOD process on nutrients for agricultural application were investigated, including organic matter, nitrogen, phosphorus, potassium and silicon contents. Layered experiments were conducted to investigate the layered variation of nutrients in sludge and to understand the potential change mechanisms. The experimental results showed that PEOD process caused small losses (<10%) of organic matter and total phosphorus (TP) in sludge, but caused 11.2−18.4% loss of total nitrogen (TN). PEOD process also caused 18.6−27.0% loss of total potassium (TK) and over 80% loss of available potassium in sludge, and could weaken the potential salt damage during the agricultural application of sludge. Furthermore, the available phosphorus content of sludge in the anode area increased significantly after the PEOD process, indicating that PEOD process could enhance the phosphorus bioavailability of sludge in the anode area. Besides, PEOD process caused a slight loss of silicon components in sludge, but improved the long-term silicon dissolution and release ability of sludge. This work could expand the knowledge about the influences of PEOD process on sludge nutrients and provide scientific guidance for the agricultural application of PEOD sludge.