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- Publisher
- Wiley
- Copyright
- "Copyright © 2015 Wiley Subscription Services, Inc., A Wiley Company"
- ISSN
- 1864-5631
- eISSN
- 1864-564X
- DOI
- 10.1002/cssc.201500694
- pmid
- 26219092
- Publisher site
- See Article on Publisher Site
Abstract
Catalysis is a key technology for the synthesis of renewable fuels through electrochemical reduction of CO2. However, successful CO2 reduction still suffers from the lack of affordable catalyst design and understanding the factors governing catalysis. Herein, we demonstrate that the CO2 conversion selectivity on Sn (or SnOx/Sn) electrodes is correlated to the native oxygen content at the subsurface. Electrochemical analyses show that the reduced Sn electrode with abundant oxygen species effectively stabilizes a CO2.− intermediate rather than the clean Sn surface, and consequently results in enhanced formate production in the CO2 reduction. Based on this design strategy, a hierarchical Sn dendrite electrode with high oxygen content, consisting of a multi‐branched conifer‐like structure with an enlarged surface area, was synthesized. The electrode exhibits a superior formate production rate (228.6 μmol h−1 cm−2) at −1.36 VRHE without any considerable catalytic degradation over 18 h of operation.
Journal
ChemSusChem - Chemistry and Sustainability, Energy & Materials – Wiley
Published: Sep 21, 2016
Keywords: ; ; ; ;