Access the full text.
Sign up today, get DeepDyve free for 14 days.
Yan Zhao, D. Truhlar (2008)
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionalsTheoretical Chemistry Accounts, 120
M. Melaimi, Rodolphe Jazzar, Michèle Soleilhavoup, G. Bertrand (2017)
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments.Angewandte Chemie, 56 34
Karlee Bamford, L. Longobardi, Lei Liu, S. Grimme, D. Stephan (2017)
FLP reduction and hydroboration of phenanthrene o-iminoquinones and α-diimines.Dalton transactions, 46 16
L. Liu, Levy Cao, Yue Shao, D. Stephan (2017)
Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation.Journal of the American Chemical Society, 139 29
A. Singh, Prinson Samuel, H. Roesky, Martin Schwarzer, G. Frenking, N. Sidhu, B. Dittrich (2013)
A singlet biradicaloid zinc compound and its nonradical counterpart.Journal of the American Chemical Society, 135 19
G. Welch, Ronan Juan, Jason Masuda, D. Stephan (2006)
Reversible, Metal-Free Hydrogen ActivationScience, 314
P. Chirik (2015)
Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands.Accounts of chemical research, 48 6
K. Kadish, L. Shiue, R. Rhodes, L. Bottomley (1981)
Reactions of metalloporphyrin .pi. radicals. 1. Complexation of zinc tetraphenylporphyrin cation and anion radicals with nitrogenous basesInorganic Chemistry, 20
W. Kaim (2011)
Manifestations of noninnocent ligand behavior.Inorganic chemistry, 50 20
D. Stephan, G. Erker (2010)
Frustrated Lewis pairs: metal-free hydrogen activation and more.Angewandte Chemie, 49 1
J. Bu'lock, J. Harley-Mason (1951)
497. Melanin and its precursors. Part III. New syntheses of 5 : 6-dihydroxyindole and its derivativesJournal of The Chemical Society (resumed)
R. Mason (1968)
Activation of Small Molecules by Transition Metal Ions and their ComplexesNature, 217
D. Stephan, G. Erker (2015)
Chemie frustrierter Lewis‐Paare: Entwicklung und PerspektivenAngewandte Chemie, 127
A. Piskunov, A. Maleeva, G. Abakumov, V. Cherkasov, G. Fukin, A. Bogomyakov (2011)
Zinc and cadmium complexes based on 3,6-di-tert-butyl-o-benzoquinoneRussian Journal of Coordination Chemistry, 37
D. Stephan, G. Erker (2015)
Frustrated Lewis pair chemistry: development and perspectives.Angewandte Chemie, 54 22
L. Liu, Levy Cao, Yue Shao, Gabriel Ménard, D. Stephan (2017)
A Radical Mechanism for Frustrated Lewis Pair ReactivityChem, 3
K. Raman, A. Kamerbeek, A. Mukherjee, N. Atodiresei, Tamal Sen, P. Lazic, V. Caciuc, Reent Michel, D. Stalke, S. Mandal, S. Blügel, M. Münzenberg, J. Moodera (2013)
Interface-engineered templates for molecular spin memory devicesNature, 493
Justin Henthorn, Sibo Lin, T. Agapie (2015)
Combination of redox-active ligand and lewis acid for dioxygen reduction with π-bound molybdenum-quinonoid complexes.Journal of the American Chemical Society, 137 4
D. Sun, E. Ehrenfreund, Z. Vardeny (2014)
The first decade of organic spintronics research.Chemical communications, 50 15
M. Hopkinson, C. Richter, M. Schedler, F. Glorius (2014)
An overview of N-heterocyclic carbenesNature, 510
David Martin, Michèle Soleilhavoup, G. Bertrand (2011)
Stable singlet carbenes as mimics for transition metal centers.Chemical science, 2 3
D. Broere, R. Plessius, J. Vlugt (2015)
New avenues for ligand-mediated processes--expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands.Chemical Society reviews, 44 19
Vijayendran Praneeth, Mark Ringenberg, Thomas Ward (2012)
Redoxaktive Liganden in der KatalyseAngewandte Chemie, 124
M. Donzello, C. Ercolani, Xiaohui Cai, K. Kadish, G. Ricciardi, A. Rosa (2009)
Tetrakis(thiadiazole)porphyrazines. 6. Spectroelectrochemical and density functional theory studies of the anions [TTDPzM](n-) (n = 1-4; M = Zn(II), Mg(II)(H(2)O), Cu(II), 2H(I)).Inorganic chemistry, 48 20
Geoffrey Spikes, J. Fettinger, P. Power (2005)
Facile activation of dihydrogen by an unsaturated heavier main group compound.Journal of the American Chemical Society, 127 35
G. Koten, J. Jastrzebski, K. Vrieze (1983)
Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic synthesesJournal of Organometallic Chemistry, 250
N. Hill, I. Vargas-Baca, A. Cowley (2009)
Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements.Dalton transactions, 2
V. Praneeth, M. Ringenberg, T. Ward (2012)
Redox-active ligands in catalysis.Angewandte Chemie, 51 41
I. Dranka, Marcin Kubisiak, I. Justyniak, M. Lesiuk, D. Kubicki, J. Lewiński (2011)
Reactions of ZnR2 compounds with dibenzoyl: characterisation of the alkyl-transfer products and a striking product-inhibition effect.Chemistry, 17 45
C. Lange, B. Conklin, C. Pierpont (1994)
Radical superexchange in semiquinone complexes containing diamagnetic metal ions. 3,6-Di-tert-butyl-1,2-semiquinonate complexes of zinc(II), cobalt(III), gallium(III), and aluminum(III)Inorganic Chemistry, 33
L. Longobardi, Lei Liu, S. Grimme, D. Stephan (2016)
Stable Borocyclic Radicals via Frustrated Lewis Pair Hydrogenations.Journal of the American Chemical Society, 138 8
Xin Zheng, Xingyong Wang, Yunfan Qiu, Yuantao Li, Chenkun Zhou, Y. Sui, Yizhi Li, Jing Ma, Xinping Wang (2013)
One-electron oxidation of an organic molecule by B(C6F5)3; isolation and structures of stable non-para-substituted triarylamine cation radical and bis(triarylamine) dication diradicaloid.Journal of the American Chemical Society, 135 40
Steven Keizer, J. Mack, Barbara Bench, S. Gorun, M. Stillman (2003)
Spectroscopy and electronic structure of electron deficient zinc phthalocyanines.Journal of the American Chemical Society, 125 23
D. Stephan (2015)
Frustrated Lewis Pairs.Journal of the American Chemical Society, 137 32
Volodymyr Lyaskovskyy, B. Bruin (2012)
Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic ReactionsACS Catalysis, 2
Jenny McCahill, G. Welch, D. Stephan (2007)
Reactivity of "frustrated Lewis pairs": three-component reactions of phosphines, a borane, and olefins.Angewandte Chemie, 46 26
J. Lewiński, Karolina Suwała, Marcin Kubisiak, Z. Ochal, I. Justyniak, J. Lipkowski (2008)
Oxygenation of a Me2Zn/alpha-diimine system: a unique zinc methylperoxide cluster and evidence for its sequential decomposition pathways.Angewandte Chemie, 47 41
Tina Tezgerevska, Kerwyn Alley, C. Boskovic (2014)
Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligandsCoordination Chemistry Reviews, 268
Andrew Mountford, S. Lancaster, S. Coles, P. Horton, D. Hughes, M. Hursthouse, M. Light (2006)
The synthesis, molecular structures, and supramolecular architecture of amine adducts of bis(pentafluorophenyl)zincOrganometallics, 25
Xiaoqun Li, Bin Wang, He-Yuan Ji, Yue-sheng Li (2016)
Insights into the mechanism for ring-opening polymerization of lactide catalyzed by Zn(C6F5)2/organic superbase Lewis pairsCatalysis Science & Technology, 6
Michèle Soleilhavoup, G. Bertrand (2015)
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.Accounts of chemical research, 48 2
A. Ożarowski, B. Mcgarvey, C. Peppe, D. Tuck (1991)
Metal(II) derivatives of 3,5-di-tert-butyl-1,2-ortho-benzoquinone. EPR study of conformation in biradicalsJournal of the American Chemical Society, 113
D. Stephan, G. Erker (2010)
Frustrierte Lewis‐Paare: metallfreie Wasserstoffaktivierung und mehrAngewandte Chemie, 122
F. Weigend, R. Ahlrichs (2005)
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy.Physical chemistry chemical physics : PCCP, 7 18
G. Frey, Vincent Lavallo, B. Donnadieu, W. Schoeller, G. Bertrand (2007)
Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon CenterScience, 316
Gabriel Ménard, Jillian Hatnean, Hugh Cowley, A. Lough, J. Rawson, D. Stephan (2013)
C-H bond activation by radical ion pairs derived from R3P/Al(C6F5)3 frustrated Lewis pairs and N2O.Journal of the American Chemical Society, 135 17
D. Stephan (2016)
The broadening reach of frustrated Lewis pair chemistryScience, 354
Beatriz Cordero, V. Gómez, Ana Platero‐Prats, M. Reves, J. Echeverría, E. Cremades, F. Barragán, S. Alvarez (2008)
Covalent radii revisited.Dalton transactions, 21
Connie Lu, E. Bill, T. Weyhermüller, E. Bothe, K. Wieghardt (2008)
Neutral bis(alpha-iminopyridine)metal complexes of the first-row transition ions (Cr, Mn, Fe, Co, Ni, Zn) and their monocationic analogues: mixed valency involving a redox noninnocent ligand system.Journal of the American Chemical Society, 130 10
P. Power (2010)
Main-group elements as transition metalsNature, 463
L. Longobardi, P. Zatsepin, Roman Korol, Lei Liu, S. Grimme, D. Stephan (2017)
Reactions of Boron-Derived Radicals with Nucleophiles.Journal of the American Chemical Society, 139 1
D. Stephan (2015)
Frustrated Lewis pairs: from concept to catalysis.Accounts of chemical research, 48 2
A. Piskunov, A. Maleeva, A. Bogomyakov, A. Starikov, G. Fukin (2015)
Structure and magnetic properties of bis-o-benzosemiquinonato zinc complexesPolyhedron, 102
Justin Henthorn, T. Agapie (2014)
Dioxygen reactivity with a ferrocene-Lewis acid pairing: reduction to a boron peroxide in the presence of tris(pentafluorophenyl)borane.Angewandte Chemie, 53 47
I. Fedushkin, A. Skatova, S. Ketkov, O. Eremenko, A. Piskunov, G. Fukin (2007)
[(dpp-bian)Zn--Zn(dpp-bian)]: A zinc-zinc-bonded compound supported by radical-anionic ligands.Angewandte Chemie, 46 23
Reactions of [Cp*2Fe] with the Lewis acid [Zn(C6F5)2] in the presence of [(PhC(S)S)2], 9,10‐phenanthrenedione or 4,5‐pyrenedione yield the salt [Cp*2Fe][(PhC(S)S)Zn(C6F5)2] 1, [Cp*2Fe][((C14H8O2)Zn(C6F5)2)⋅] 4, and [Cp*2Fe][((C16H8O2)Zn(C6F5)2)⋅] 5, respectively. The latter two species represent the first examples of isolable zinc‐containing radical anions. While [(PhC(S)S)2] binds weakly to [Zn(C6F5)2], the diones afford the isolable adducts [(C14H8O2)Zn(C6F5)2] 2 and [(C16H8O2)Zn(C6F5)2] 3. Cyclic voltammetry and computational studies support the view that 4 and 5 are formed via single electron transfer (SET) to the donor–acceptor adducts, 2 and 3, respectively. Subsequent treatment of 4 and 5 with [NC5H4NMe2] affords [Zn(C6F5)2(NC5H4NMe2)2] with liberation of the dione, and regeneration of [Cp*2Fe].
Chemistry - A European Journal – Wiley
Published: Mar 15, 2019
Keywords: ; ; ; ;
Access the full text.
Sign up today, get DeepDyve free for 14 days.