Surface‐initiated atom transfer radical polymerization of a new rhodanine‐based monomer for rapid magnetic removal of Co(II) ions from aqueous solutions

Surface‐initiated atom transfer radical polymerization of a new rhodanine‐based monomer for... The present study reports synthesis and characterization of a new acrylamide‐based monomer containing rhodanine moiety, N‐3‐amino‐thiazolidine‐4‐one‐acrylamide (ATA). Poly(ATA)‐grafted magnetite nanoparticles (poly(ATA)‐g‐MNPs) were prepared using surface‐initiated atom transfer radical polymerization of the monomer on Fe3O4 nanoparticles. The grafted nanoparticles were characterized by Fourier transform infrared analysis, scanning electron microscopy, X‐ray diffraction, and vibrating sample magnetometry. The amount of the grafted polymer was 209 mg g−1, as calculated from thermogravimetric analysis experiment. The capability of poly(ATA)‐g‐MNPs to remove Co(II) cations was shown under optimal conditions of contact time, pH, adsorbent dosage, and initial Co(II) concentration. About 86% of the Co(II) cations were removed over 7 minutes. The adsorption kinetics obeyed the pseudo–second‐order kinetic equation, and the Langmuir isotherm model best described the adsorption isotherm with a maximum adsorption capacity of 3.62 mg g−1. The thermodynamic investigation showed spontaneous nature of the adsorption process (ΔG = −2.90 kJ mol−1 at 25°C ± 1°C). In addition, the poly(ATA)‐g‐MNPs were regenerated by simply washing with an aqueous 0.1M HCl solution. The study of the reusability of the prepared magnetic sorbent revealed that the sorbent can be reused without a significant decrease in the extraction efficiency and be recovered by 95.4% after 7 cycles. These findings suggest that the grafted nanoparticles are stable and reusable adsorbent and can be potentially applied to water treatment in efficient removal of Co(II) cations. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Polymers for Advanced Technologies Wiley

Surface‐initiated atom transfer radical polymerization of a new rhodanine‐based monomer for rapid magnetic removal of Co(II) ions from aqueous solutions

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Publisher
Wiley
Copyright
Copyright © 2018 John Wiley & Sons, Ltd.
ISSN
1042-7147
eISSN
1099-1581
DOI
10.1002/pat.4307
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Abstract

The present study reports synthesis and characterization of a new acrylamide‐based monomer containing rhodanine moiety, N‐3‐amino‐thiazolidine‐4‐one‐acrylamide (ATA). Poly(ATA)‐grafted magnetite nanoparticles (poly(ATA)‐g‐MNPs) were prepared using surface‐initiated atom transfer radical polymerization of the monomer on Fe3O4 nanoparticles. The grafted nanoparticles were characterized by Fourier transform infrared analysis, scanning electron microscopy, X‐ray diffraction, and vibrating sample magnetometry. The amount of the grafted polymer was 209 mg g−1, as calculated from thermogravimetric analysis experiment. The capability of poly(ATA)‐g‐MNPs to remove Co(II) cations was shown under optimal conditions of contact time, pH, adsorbent dosage, and initial Co(II) concentration. About 86% of the Co(II) cations were removed over 7 minutes. The adsorption kinetics obeyed the pseudo–second‐order kinetic equation, and the Langmuir isotherm model best described the adsorption isotherm with a maximum adsorption capacity of 3.62 mg g−1. The thermodynamic investigation showed spontaneous nature of the adsorption process (ΔG = −2.90 kJ mol−1 at 25°C ± 1°C). In addition, the poly(ATA)‐g‐MNPs were regenerated by simply washing with an aqueous 0.1M HCl solution. The study of the reusability of the prepared magnetic sorbent revealed that the sorbent can be reused without a significant decrease in the extraction efficiency and be recovered by 95.4% after 7 cycles. These findings suggest that the grafted nanoparticles are stable and reusable adsorbent and can be potentially applied to water treatment in efficient removal of Co(II) cations.

Journal

Polymers for Advanced Technologies – Wiley

Published: Jan 1, 2018

Keywords: ; ; ; ;

References

  • Triphenylamine‐based fluorescent conjugated copolymers with pendant terpyridyl ligands as chemosensors for metal ions
    Cui, Y; Chen, Q; Zhang, D‐D; Cao, J; Han, B‐H
  • Heavy metal adsorbents prepared from the modification of cellulose: a review
    O'Connell, DW; Birkinshaw, C; O'Dwyer, TF
  • Comparisons of low‐cost adsorbents for treating wastewaters laden with heavy metals
    Kurniawan, TA; Chan, GYS; Lo, W‐H; Babel, S
  • Solid phase extraction of Cu2+, Ni2+, and Co2+ ions by a new magnetic nano‐composite: excellent reactivity combined with facile extraction and determination
    Azizi, P; Golshekan, M; Shariati, S; Rahchamani, J
  • Review of metal sulphide precipitation
    Lewis, AE
  • Removal of heavy metals from wastewater using micellar enhanced ultrafiltration technique: a review
    Mungray, AA; Kulkarni, SV; Mungray, AK
  • Interaction of heavy metal ions with an ion exchange resin obtained from a natural polyelectrolyte
    Maturana, HA; Perič, IM; Rivas, BL; Amalia Pooley, S
  • A novel polyvinyltetrazole‐grafted resin with high capacity for adsorption of Pb(II), Cu(II) and Cr(III) ions from aqueous solutions
    Chen, Y; He, M; Wang, C; Wei, Y
  • Preparation of porous resin with Schiff base chelating groups for removal of heavy metal ions from aqueous solutions
    Cegłowski, M; Schroeder, G
  • Extraction and recycling utilization of metal ions (Cu2+, Co2+ and Ni2+) with magnetic polymer beads
    Lin, Z; Zhang, Y; Chen, Y; Qian, H
  • Enhanced heavy metals removal and recovery by mesoporous adsorbent prepared from waste rubber tire
    Gupta, VK; Ganjali, MR; Nayak, A; Bhushan, B; Agarwal, S
  • Chemistry and biological activity of thiazolidinones
    Singh, SP; Parmar, SS; Raman, K; Stenberg, VI
  • Simultaneous determination of gold and palladium with 5(p‐dimethylaminobenzylidene)rhodanine by using the H‐point standard addition method in micellar media
    Pourreza, N; Rastegarzadeh, S
  • Highly sensitive and selective spectrophotometric method for determination of trace gold in geological samples with 5‐(2‐hydroxy‐5‐nitrophenylazo)rhodanine
    Zaijun, L; Jiaomai, P; Jian, T
  • Selective solid phase extraction of palladium by adsorption of its 5(p‐dimethylaminobenzylidene)rhodanine complex on silica‐PEG as a new adsorbent
    Rastegarzadeh, S; Pourreza, N; Kiasat, AR; Yahyavi, H
  • Superparamagnetic maghemite/polyrhodanine core/shell nanoparticles: synthesis and characterization
    Seraj, S; Mirzayi, B; Nematollahzadeh, A
  • Synthesis of rhodanine‐bonded silica gel and its application in the preconcentration and separation of noble metals
    Liu, P; Pu, QS; Sun, QY; Su, ZX
  • Rhodanine stabilized gold nanoparticles for sensitive and selective detection of mercury (II)
    Chen, Y; Han, S; Yang, S; Pu, Q
  • Rapid ionic liquid‐based ultrasound assisted dual magnetic microextraction to preconcentrate and separate cadmium‐4‐(2‐thiazolylazo)‐resorcinol complex from environmental and biological samples
    Khan, S; Kazi, TG; Soylak, M
  • Synthesis of Fe3O4 nanoparticles and their magnetic properties
    Wei, Y; Han, B; Hu, X; Lin, Y; Wang, X; Deng, X
  • Mercury (II) removal with modified magnetic chitosan adsorbents
    Kyzas, GZ; Deliyanni, EA
  • Adsorption of hg(II) from aqueous solutions by thiol‐functionalized polymer‐coated magnetic particles
    Jainae, K; Sukpirom, N; Fuangswasdi, S; Unob, F
  • Magnetic adsorbents based on micro‐ and nano‐structured materials
    Kharissova, OV; Dias, HVR; Kharisov, BI
  • Aqueous Co(II) adsorption using 8‐hydroxyquinoline anchored γ‐Fe2O3@chitosan with Co(II) as imprinted ions
    Hossein Beyki, M; Shemirani, F; Shirkhodaie, M
  • Preparation of magnetic Carboxymethylchitosan nanoparticles for adsorption of heavy metal ions
    Charpentier, TVJ; Neville, A; Lanigan, JL; Barker, R; Smith, MJ; Richardson, T
  • A new magnetic ion‐imprinted polymer as a highly selective sorbent for determination of cobalt in biological and environmental samples
    Khoddami, N; Shemirani, F
  • Solution behaviour of hydrophobically modified hydrolysed alternating copolymersm of maleic anhydride and propene
    Werner, K; Komber, H; Reinhardt, S; Steinert, V
  • Amino functionalized ATRP‐prepared polyacrylamide‐g‐magnetite nanoparticles for the effective removal of Cu(II) ions: kinetics investigations
    Mirzaeinejad, M; Mansoori, Y; Amiri, M
  • New acrylamide‐based monomer containing metal chelating units: Homopolymer grafted magnetite nanoparticles via ATRP for the magnetic removal of Co(II) ions
    Mirzaeinejad, M; Mansoori, Y; Koohi‐Zargar, B
  • A new insight on the adsorption mechanism of amino‐functionalized nano‐Fe3O4 magnetic polymers in Cu(II), Cr(VI) co‐existing water system
    Shen, H; Pan, S; Zhang, Y; Huang, X; Gong, H
  • Removal of metal ions from water using poly(MMA‐co‐MA)/modified‐Fe3O4 magnetic nanocomposite: isotherm and kinetic study
    Masoumi, A; Ghaemy, M; Bakht, AN
  • Adsorption of hexavalent chromium onto magnetic natural zeolite‐polymer composite
    Mthombeni, NH; Onyango, MS; Aoyi, O
  • Application of magnetic nanoparticles modified with poly(2‐amino thiophenol) as a sorbent for solid phase extraction and trace detection of lead, copper and silver ions in food matrices
    Sedghi, R; Shojaee, M; Behbahani, M; Nabid, MR
  • Chelating magnetic copolymer composite modified by click reaction for removal of heavy metal ions from aqueous solution
    Lapwanit, S; Trakulsujaritchok, T; Nongkhai, PN
  • Synthesis, characterization and using at the copper adsorption of chitosan/polyvinyl alcohol magnetic composite
    Karaer, H; Kaya, İ
  • Polyacrylamide grafted attapulgite (PAM‐ATP) via surface‐initiated atom transfer radical polymerization (SI‐ATRP) for removal of Hg(II) ion and dyes
    Liu, P; Guo, J
  • Modification of poly(hydroethyl acrylate)‐grafted cross‐linked poly(vinyl chloride) particles via surface‐initiated atom‐transfer radical polymerization (SI‐ATRP). Competitive adsorption of some heavy metal ions on modified polymers
    Liu, P; Liu, Y; Su, Z
  • Efficient removal of Cu(II), Pb(II), Cr(VI) and As(V) from aqueous solution using an aminated resin prepared by surface‐initiated atom transfer radical polymerization
    Niu, L; Deng, S; Yu, G; Huang, J
  • Fe3O4‐PVAc nanocomposites: surface modification of sonochemically prepared magnetite nanoparticles via chemical grafting of poly(vinyl acetate)
    Mansoori, Y; Khodayari, A; Banaei, A; Mirzaeinejad, M; Azizian‐Kalandaragh, Y; Pooresmaeil, M
  • Structural and spectral perspectives of a novel thiosemicarbazone synthesized from di‐2‐pyridyl ketone and 4‐phenyl‐3‐thiosemicarbazide
    Suni, V; Prathapachandra Kurup, MR; Nethaji, M
  • Standard methods for the examination of water and wastewater
  • Surface initiated ATRP in the synthesis of iron oxide/polystyrene core/shell nanoparticles
    Sun, Y; Ding, X; Zheng, Z; Cheng, X; Hu, X; Peng, Y
  • Surface modification of magnetite nanoparticle with azobenzene‐containing water dispersible polymer
    Theamdee, P; Traiphol, R; Rutnakornpituk, B; Wichai, U; Rutnakornpituk, M
  • Novel POBD‐modified organoclay and its polyimide nanocomposites for removal of the Co(II) ion
    Mansoori, Y; Fathollahi, K; Zamanlou, MR; Imanzadeh, G
  • Nanocrystalline and nanocomposite magnetic materials and their applications
    Shull, RD
  • Synthesis of poly(vinyl acetate)‐based magnetic polymer microparticles
    Ferreira, GR; Segura, T; Souza Jr, FG; Umpierre, AP; Machado, F
  • Investigation on magnetically controlled delivery of doxorubicin from superparamagnetic nanocarriers of gelatin crosslinked with genipin
    Choubey, J; Bajpai, AK
  • Characterization and magnetic properties of conducting poly(N‐vinylcarbazole)‐capped magnetite nanocomposite Langmuir‐Schaefer films
    Basavaraja, C; Jo, EA; Huh, DS
  • Grafting of water‐soluble sulfonated monomers onto functionalized fumed silica nanoparticles via surface‐initiated redox polymerization in aqueous medium
    Abdollahi, M; Rouhani, M; Hemmati, M; Salarizadeh, P
  • Mono‐organomercury and diorganothallium derivatives of rhodanine: crystal structure of dimethyl(rhodaninato)thallium(III)
    Playá, N; Macías, A; Ma Varela, J; Sánchez, A; Casas, JS; Sordo, J
  • Photochemical complexation reactions of M(CO)6 (M = Cr, Mo, W) and Re(CO)5Br with rhodanine (4‐thiazolidinone‐2‐thioxo) and 5‐substituted rhodanines
    Subasi, E; Ercag, A; Sert, S; Senturk, OS
  • Chemistry of the thiazolidinone alone or along with thiourea substituted amine complexes of zinc (II)
    Saxena, A; Upadhyay, R
  • Zur Theorie der Sogenannten Absorption gelöster Stoffe
    Lagergren, S
  • Sorption of dye from aqueous solution by peat
    Ho, YS; McKay, G
  • Chitosan functionalized with 2[‐bis‐(pyridylmethyl) aminomethyl]4‐methyl‐6‐formyl‐phenol: equilibrium and kinetics of copper (II) adsorption
    Justi, KC; Laranjeira, MCM; Neves, A; Mangrich, AS; Fávere, VT
  • Chitosan crosslinked with a metal complexing agent: synthesis, characterization and copper(II) ions adsorption
    Vasconcelos, HL; Camargo, TP; Gonçalves, NS; Neves, A; Laranjeira, MCM; Fávere, VT
  • Adsorption of cobalt(II) from aqueous solutions by Fe3O4/bentonite nanocomposite
    Hashemian, S; Saffari, H; Ragabion, S
  • A new magnetic nanocomposite for selective detection and removal of trace copper ions from water
    Qiu, X; Li, N; Yang, S
  • Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water
    Rajput, S; Pittman Jr, CU; Mohan, D
  • Efficient removal of Cu(II) and Pb(II) heavy metal ions from water samples using 2,4‐dinitrophenylhydrazine loaded sodium dodecyl sulfate‐coated magnetite nanoparticles
    Sobhanardakani, S; Ahmadi, M; Zandipak, R
  • Gum ghatti and Fe3O4 magnetic nanoparticles based nanocomposites for the effective adsorption of methylene blue from aqueous solution
    Mittal, H; Ballav, N; Mishra, SB
  • Synthesis of carboxymethyl‐β‐cyclodextrin conjugated magnetic nano‐adsorbent for removal of methylene blue
    Badruddoza, AZM; Hazel, GSS; Hidajat, K; Uddin, MS
  • Adsorption of cobalt by activated carbon from the rice hulls
    Teker, M; Saltabaş, Ö; İmamoğlu, M
  • Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite
    Yavuz, Ö; Altunkaynak, Y; Güzel, F
  • Removal of lead copper chromium and cobalt ions onto granular activated carbon in batch and fixed‐bed adsorbers
    Sulaymon, AH; Abid, BA; Al‐Najar, JA
  • Adsorption of cobalt(II) ions from aqueous solutions by palygorskite
    He, M; Zhu, Y; Yang, Y; Han, B; Zhang, Y
  • Preparation of SiO2/Nb2O5/ZnO mixed oxide by sol–gel method and its application for adsorption studies and on‐line preconcentration of cobalt ions from aqueous medium
    Diniz, KM; Gorla, FA; Ribeiro, ES

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