The reaction between aqueous solution of Me3SnCl and acetonitrile solution of quinaldic acid (quinH) at room temperature affords a new organotin complex, [Me3Sn(quinH)(quin)]⋅6H2O (1). Complex 1 was structurally characterized using infrared, UV–visible and NMR spectra, thermogravimetric analysis and single‐crystal X‐ray analysis. The network structure of 1 is developed by a limitless number of discrete mononuclear molecules forming a one‐dimensional chain via hydrogen bonds. Extensive hydrogen bonds and π–π stacking associate the one‐dimensional chains creating a two‐dimensional array. The two‐dimensional arrays are additionally associated via hydrogen bonds through the water molecules and the methyl groups forming a three‐dimensional network. The cytotoxic impact of 1 on the viability of MCF‐7 cells was also examined using MTT assay, exhibiting great inhibiting action against MCF‐7 cells. Furthermore, the catalytic degradation performance of 1 towards methylene blue dye in the presence of H2O2 as oxidant was investigated. The reaction is first order with respect to methylene blue dye.
Applied Organometallic Chemistry – Wiley
Published: Jan 1, 2018
Keywords: ; ; ;
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera