Remarkable Carbon Dioxide Hydrogenation to Ethanol on a Palladium/Iron Oxide Single‐Atom Catalyst

Remarkable Carbon Dioxide Hydrogenation to Ethanol on a Palladium/Iron Oxide Single‐Atom Catalyst The hydrogenation of CO2 into value‐added chemicals is one of the most investigated methods to reduce CO2 emissions in the atmosphere and thereby contributes to a sustainable chemical industry. Whereas the catalytic hydrogenation of CO2 into methanol and synthetic hydrocarbons is well established, the effective and selective transformation of CO2 into higher alcohols is still challenging. Here, we show that Pd single atoms anchored on the surface of Fe3O4 are very active for the hydrogenation of CO2 to ethanol at 300 °C, even at atmospheric pressure. By comparing various Pd/MOx catalysts, we conclude that the metal–oxide interface has a strong influence on catalytic behavior. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemCatChem (Electronic) Wiley

Remarkable Carbon Dioxide Hydrogenation to Ethanol on a Palladium/Iron Oxide Single‐Atom Catalyst

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Publisher
Wiley Subscription Services, Inc., A Wiley Company
Copyright
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1867-3880
eISSN
1867-3899
D.O.I.
10.1002/cctc.201800362
Publisher site
See Article on Publisher Site

Abstract

The hydrogenation of CO2 into value‐added chemicals is one of the most investigated methods to reduce CO2 emissions in the atmosphere and thereby contributes to a sustainable chemical industry. Whereas the catalytic hydrogenation of CO2 into methanol and synthetic hydrocarbons is well established, the effective and selective transformation of CO2 into higher alcohols is still challenging. Here, we show that Pd single atoms anchored on the surface of Fe3O4 are very active for the hydrogenation of CO2 to ethanol at 300 °C, even at atmospheric pressure. By comparing various Pd/MOx catalysts, we conclude that the metal–oxide interface has a strong influence on catalytic behavior.

Journal

ChemCatChem (Electronic)Wiley

Published: Jan 7, 2018

Keywords: ; ; ; ;

References

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