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C. Palocci, A. Barbetta, Angelo Grotta, M. Dentini (2007)
Porous biomaterials obtained using supercritical CO 2- water emulsions.Langmuir : the ACS journal of surfaces and colloids, 23 15
Shoucun Zhang, W. Luo, Wei Yan, B. Tan (2014)
Synthesis of a CO2-philic poly(vinyl acetate)-based cationic amphiphilic surfactant by RAFT/ATRP and its application in preparing monolithic materialsGreen Chemistry, 16
Hyunsuk Lee, J. Pack, Wenxin Wang, K. Thurecht, S. Howdle (2010)
Synthesis and Phase Behavior of CO2-Soluble Hydrocarbon Copolymer: Poly(vinyl acetate-alt-dibutyl maleate)Macromolecules, 43
F. O'Brien, B. Harley, I. Yannas, L. Gibson (2005)
The effect of pore size on cell adhesion in collagen-GAG scaffolds.Biomaterials, 26 4
A. Saeed, D. Georget, A. Mayes (2010)
Synthesis, characterisation and solution thermal behaviour of a family of poly (N-isopropyl acrylamide-co-N-hydroxymethyl acrylamide) copolymersReactive & Functional Polymers, 70
R. Butler, I. Hopkinson, A. Cooper (2003)
Synthesis of porous emulsion-templated polymers using high internal phase CO2-in-water emulsions.Journal of the American Chemical Society, 125 47
Irena Pulko, P. Krajnc (2012)
High internal phase emulsion templating--a path to hierarchically porous functional polymers.Macromolecular rapid communications, 33 20
W. Luo, Shoucun Zhang, Peng-bin Li, R. Xu, Yuexuan Zhang, Liyun Liang, C. Wood, Qunwei Lu, B. Tan (2015)
Surfactant-free CO2-in-water emulsion-templated poly (vinyl alcohol) (PVA) hydrogelsPolymer, 61
A. Menner, A. Bismarck (2006)
New Evidence for the Mechanism of the Pore Formation in Polymerising High Internal Phase Emulsions or Why polyHIPEs Have an Interconnected Pore Network StructureMacromolecular Symposia, 242
Wendy Busby, N. Cameron, C. Jahoda (2001)
Emulsion-Derived Foams (PolyHIPEs) Containing Poly(ε-caprolactone) as Matrixes for Tissue EngineeringBiomacromolecules, 2
W. Luo, R. Xu, Yunfeiyue Liu, I. Hussain, Qunwei Lu, B. Tan (2015)
Emulsion-templated poly(acrylamide)s by using polyvinyl alcohol (PVA) stabilized CO2-in-water emulsions and their applications in tissue engineering scaffoldsRSC Advances, 5
G. Pound, F. Aguesse, James McLeary, R. Lange, B. Klumperman (2007)
Xanthate-Mediated Copolymerization of Vinyl Monomers for Amphiphilic and Double-Hydrophilic Block Copolymers with Poly(ethylene glycol)Macromolecules, 40
Zhimin Xue, Wei-Shing Chang, Yanchao Cheng, Jing Liu, Jian Li, Wancheng Zhao, Tiancheng Mu (2016)
CO2-in-PEG emulsion-templating synthesis of poly(acrylamide) with controllable porosity and their use as efficient catalyst supportsRSC Advances, 6
B. Tan, Jun-Young Lee, A. Cooper (2007)
Synthesis of emulsion-templated poly(acrylamide) using CO2-in-water emulsions and poly(vinyl acetate)-based block copolymer surfactantsMacromolecules, 40
Jun Chen, Mingzhu Liu, Hongliang Liu, Liwei Ma (2009)
Synthesis, swelling and drug release behavior of poly(N,N-diethylacrylamide-co-N-hydroxymethyl acrylamide) hydrogelMaterials Science and Engineering: C, 29
M. Bokhari, Ross Carnachan, S. Przyborski, N. Cameron (2007)
Emulsion-templated porous polymers as scaffolds for three dimensional cell culture: effect of synthesis parameters on scaffold formation and homogeneityJournal of Materials Chemistry, 17
H. Tai, A. Sergienko, M. Silverstein (2001)
High internal phase emulsion foams: Copolymers and interpenetrating polymer networksPolymer Engineering and Science, 41
B. Tan, A. Cooper (2005)
Functional oligo(vinyl acetate) CO2-philes for solubilization and emulsification.Journal of the American Chemical Society, 127 25
Melanie Köllmer, Vandana Keskar, T. Hauk, J. Collins, B. Russell, R. Gemeinhart (2012)
Stem cell-derived extracellular matrix enables survival and multilineage differentiation within superporous hydrogels.Biomacromolecules, 13 4
G. Gürdağ, Gökay Öz (2009)
A novel poly(N‐isopropylacrylamide‐co‐N‐hydroxymethyl acrylamide) gel: preparation in the absence/presence of a pore‐forming agent and characterizationPolymers for Advanced Technologies, 20
M. O'neill, Q. Cao, M. Fang, K. Johnston, S. Wilkinson, C. Smith, J. Kerschner, S. Jureller (1998)
Solubility of homopolymers and copolymers in carbon dioxideIndustrial & Engineering Chemistry Research, 37
G. Gürdağ, S. Çavuş (2006)
Synthesis and swelling behavior of poly(2‐dimethylaminoethyl methacrylate‐co‐N‐hydroxymethyl acrylamide) hydrogelsPolymers for Advanced Technologies, 17
Cédric Boyère, Audrey Favrelle, Alexandre Léonard, F. Boury, C. Jérôme, Antoine Debuigne (2013)
Macroporous poly(ionic liquid) and poly(acrylamide) monoliths from CO2-in-water emulsion templates stabilized by sugar-based surfactantsJournal of Materials Chemistry, 1
Céline Lucchesi, Sagrario Pascual, G. Dujardin, L. Fontaine (2008)
New functionalized polyHIPE materials used as amine scavengers in batch and flow-through processesReactive & Functional Polymers, 68
Cédric Boyère, Alexandre Léonard, B. Grignard, Audrey Favrelle, J. Pirard, M. Paquot, C. Jérôme, Antoine Debuigne (2012)
Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide.Chemical communications, 48 67
C. Lee, Petros Psathas, K. Johnston, J. deGrazia, T. Randolph (1999)
Water-in-carbon dioxide emulsions: Formation and stabilityLangmuir, 15
A. Menner, R. Powell, A. Bismarck (2006)
A new route to carbon black filled polyHIPEs.Soft matter, 2 4
G. Jacobson, C. Lee, K. Johnston, W. Tumas (1999)
Enhanced catalyst reactivity and separations using water/carbon dioxide emulsions [5]Journal of the American Chemical Society, 121
E. Beckman (2004)
Supercritical and near-critical CO2 in green chemical synthesis and processingJournal of Supercritical Fluids, 28
Irena Pulko, Jennifer Wall, P. Krajnc, N. Cameron (2010)
Ultra-high surface area functional porous polymers by emulsion templating and hypercrosslinking: efficient nucleophilic catalyst supports.Chemistry, 16 8
Keping Chen, N. Grant, Liyun Liang, Haifei Zhang, B. Tan (2010)
Synthesis of CO2-philic Xanthate−Oligo(vinyl acetate)-Based Hydrocarbon Surfactants by RAFT Polymerization and Their Applications on Preparation of Emulsion-Templated MaterialsMacromolecules, 43
Varun Dhanuka, J. Dickson, W. Ryoo, K. Johnston (2006)
High internal phase CO2-in-water emulsions stabilized with a branched nonionic hydrocarbon surfactant.Journal of colloid and interface science, 298 1
S. Partap, I. Rehman, Julian Jones, J. Darr (2006)
“Supercritical Carbon Dioxide in Water” Emulsion‐Templated Synthesis of Porous Calcium Alginate HydrogelsAdvanced Materials, 18
Jun-Young Lee, B. Tan, A. Cooper (2007)
CO2-in-Water Emulsion-Templated Poly(vinyl alcohol) Hydrogels Using Poly(vinyl acetate)-Based SurfactantsMacromolecules, 40
C. Youssef, R. Backov, M. Tréguer, M. Birot, H. Deleuze (2010)
Preparation of remarkably tough polyHIPE materials via polymerization of oil‐in‐water HIPEs involving 1‐vinyl‐5‐aminotetrazoleJournal of Polymer Science Part A, 48
B. Yıldız, B. Işık, M. Kiş (2001)
Synthesis of thermoresponsive N-isopropylacrylamide–N-hydroxymethyl acrylamide hydrogels by redox polymerizationPolymer, 42
I. Yannas (1992)
Tissue regeneration by use of collagen-glycosaminoglycan copolymers.Clinical materials, 9 3-4
Yingwu Luo, An-Ni Wang, Xiang-Jie Gao (2012)
Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerizationSoft Matter, 8
Jenny Normatov, M. Silverstein (2007)
Silsesquioxane-cross-linked porous nanocomposites synthesized within high internal phase emulsionsMacromolecules, 40
N. Annabi, J. Nichol, Xiamei Zhong, Chengdong Ji, Sandeep Koshy, A. Khademhosseini, F. Dehghani (2010)
Controlling the porosity and microarchitecture of hydrogels for tissue engineering.Tissue engineering. Part B, Reviews, 16 4
Chun-tian Zhao, E. Danish, N. Cameron, R. Kataky (2007)
Emulsion-templated porous materials (PolyHIPEs) for selective ion and molecular recognition and transport: applications in electrochemical sensingJournal of Materials Chemistry, 17
Yulia Lumelsky, J. Zoldan, S. Levenberg, M. Silverstein (2008)
Porous Polycaprolactone-Polystyrene Semi-interpenetrating Polymer Networks Synthesized within High Internal Phase EmulsionsMacromolecules, 41
N. Annabi, S. Mithieux, A. Weiss, F. Dehghani (2010)
Cross-linked open-pore elastic hydrogels based on tropoelastin, elastin and high pressure CO2.Biomaterials, 31 7
R. Butler, C. Davies, A. Cooper (2001)
Emulsion Templating Using High Internal Phase Supercritical Fluid EmulsionsAdvanced Materials, 13
Poly(vinyl acetate‐alt‐dibutyl maleate)‐block‐poly(ethylene glycol) (PVDBM‐b‐PEG) copolymers were synthesized via reversible addition–fragmentation chain transfer radical polymerization and used as emulsifiers to form stable CO2‐in‐water high internal phase emulsions (C/W HIPEs). Then, highly interconnected cellular polyacrylamide (PAM) and poly(acrylamide‐co‐N‐hydroxymethyl acrylamide) [P(AM‐co‐HMAM)] poly‐HIPEs with enhanced mechanical strength were prepared based on the stable C/W HIPEs. The porous structures of the PAM poly‐HIPEs, as well as morphology and compressive modulus, could be influenced by the surfactant concentration and the length of the CO2‐philic tails of the surfactants. PAM poly‐HIPEs with the smallest average pore diameter (11.12 ± 0.62 μm) and the highest compressive modulus (22.65 ± 0.10 MPa) could be obtained by using the short CO2‐philic chains of the PVDBM‐b‐PEG surfactant at a high concentration (1.0 wt %). Moreover, with the copolymerization of N‐hydroxymethyl acrylamide (HMAM) comonomers with acrylamide, the compressive modulus of the obtained P(AM‐co‐HMAM) poly‐HIPEs was three times higher than that of PAM poly‐HIPEs. Both PAM and P(AM‐co‐HMAM) poly‐HIPEs were employed as scaffolds to guide H9c2 cardiac muscle cellular growth. Fluorescence images showed that a smaller average pore size and a narrower pore‐size distribution were helpful for cell growth and proliferation on these materials. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46346.
Journal of Applied Polymer Science – Wiley
Published: Jan 15, 2018
Keywords: ; ; ; ;
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