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Photo‐induced isomerization of 8‐(3,4,5‐trimethoxystyryl)caffeine as possible route of drug decomposition

10.1002/jps.2600621136.abs trans‐8‐(3,4,5‐Trimethoxystyryl)caffeine, dissolved in methanol or chloroform, rapidly isomerizes to an equilibrium mixture of trans‐cis‐isomers in the presence of visible light. Geometric isomerization was established by catalytic hydrogenation of both reactant and product to yield 8‐(3,4,5‐trimethoxyphenethyl)caffeine. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Pharmaceutical Science Wiley

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