Perylene‐based Solution‐processable Conjugated Molecules for Optoelectronic Applications: Synthesis and Comparison of Different Substituents on the Optical, Thermal, and Electrochemical Properties

Perylene‐based Solution‐processable Conjugated Molecules for Optoelectronic Applications:... A series of small organic molecules were synthesized by exploiting the bay and imide positions of the perylene nucleus. The synthesized compounds 1–11 were characterized by spectroscopic and elemental analyses. These molecules show yellowish color in solution and are highly soluble in dichloromethane. Compound 7 shows a bandgap of 1.7 eV and a Stokes shift of 27. From these results, we infer that this compound can serve as structural template in the design of organic electronics. Moreover, compound 7 shows higher Td (370°C) and Tg (132°C) values, which reflect its high thermal stability. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of the Chinese Chemical Society Wiley

Perylene‐based Solution‐processable Conjugated Molecules for Optoelectronic Applications: Synthesis and Comparison of Different Substituents on the Optical, Thermal, and Electrochemical Properties

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Publisher
Wiley
Copyright
© 2018 The Chemical Society Located in Taipei & Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
0009-4536
eISSN
2192-6549
D.O.I.
10.1002/jccs.201700087
Publisher site
See Article on Publisher Site

Abstract

A series of small organic molecules were synthesized by exploiting the bay and imide positions of the perylene nucleus. The synthesized compounds 1–11 were characterized by spectroscopic and elemental analyses. These molecules show yellowish color in solution and are highly soluble in dichloromethane. Compound 7 shows a bandgap of 1.7 eV and a Stokes shift of 27. From these results, we infer that this compound can serve as structural template in the design of organic electronics. Moreover, compound 7 shows higher Td (370°C) and Tg (132°C) values, which reflect its high thermal stability.

Journal

Journal of the Chinese Chemical SocietyWiley

Published: Jan 1, 2018

Keywords: ; ; ; ; ;

References

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