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Hsiang-Lin Yu, T. Lin (1983)
Spin density distribution of the photoexcited triplet state of anthracene via electron spin echo envelope modulation spectroscopyChemical Physics Letters, 102
A. Henstra, T. Lin, W. Wenckebach (1991)
Muon spin rotation (μSR) detected electron spin echo envelope modulation (ESEEM)Physics Letters A, 157
M. Kinoshita, N. Iwasaki, N. Nishi (1981)
Molecular Spectroscopy of the Triplet State through Optical Detection of Zero-Field Magnetic ResonanceApplied Spectroscopy Reviews, 17
R. Rajagopalan, T. Lin, A. Karwa, A. Poreddy, B. Asmelash, R. Dorshow (2012)
Type 1 Phototherapeutic Agents. 2. Cancer Cell Viability and ESR Studies of Tricyclic Diarylamines.ACS medicinal chemistry letters, 3 4
A. Mohorič, J. Stepišnik (2009)
NMR in the Earth’s magnetic fieldProgress in Nuclear Magnetic Resonance Spectroscopy, 54
K. Takeda, K. Takegoshi, T. Terao (2004)
Dynamic Nuclear Polarization by Electron Spins in the Photoexcited Triplet State: I. Attainment of Proton Polarization of 0.7 at 105 K in NaphthaleneJournal of the Physical Society of Japan, 73
J. Ong, D. Sloop, T. Lin (1993)
Temperature dependence studies of the paramagnetic properties of the photoexcited triplet states of pentacene in p-terphenyl, benzoic acid, and naphthalene crystalsThe Journal of Physical Chemistry, 97
R. Hochstrasser, T. Lin (1968)
Magnetic and Electric Field Spectra of Organic Crystals: Optical Measurements of Zero‐Field SplittingsJournal of Chemical Physics, 49
T. Yago, G. Link, G. Kothe, T. Lin (2007)
Pulsed electron nuclear double resonance studies of the photoexcited triplet state of pentacene in p-terphenyl crystals at room temperature.The Journal of chemical physics, 127 11
P. Massé, S. Reculusa, Koen Clays, S. Ravaine (2006)
Tailoring planar defect in three-dimensional colloidal crystalsChemical Physics Letters, 422
V. Kouskov, D. Sloop, S. Liu, T. Lin (1999)
Dynamic nuclear polarization in pulsed ENDOR experiments.Journal of magnetic resonance, 137 1
A. Abragam, M. Goldman (1978)
Principles of dynamic nuclear polarisationReports on Progress in Physics, 41
D. Sloop, T. Lin (1990)
Spin-echo-ENDOR studies of the photoexcited triplet state of pentacene in p-terphenyl crystals at room temperatureJournal of Magnetic Resonance, 86
Qingbo Yang, T. Lin, Casey Burton, Sunghee Park, Yinfa Ma (2016)
Physicochemical insights of irradiation-enhanced hydroxyl radical generation from ZnO nanoparticles.Toxicology research, 5 2
Tran-chin Yang, D. Sloop, S. Weissman, T. Lin (2002)
Magnetic effects on the dynamics of organic triplets in the level anti-crossing regionMolecular Physics, 100
C. Cheng, T. Lin, D. Sloop (1979)
Electron spin-echo experiments of diphenylnitroxide in benzophenone crystalsJournal of Magnetic Resonance, 33
A. Henstra, T. Lin, Jan Schmidt, W. Wenckebach (1990)
High dynamic nuclear polarization at room temperatureChemical Physics Letters, 165
M. Rosay, L. Tometich, S. Pawsey, R. Bader, R. Schauwecker, M. Blank, P. Borchard, S. Cauffman, K. Felch, R. Weber, R. Temkin, R. Griffin, W. Maas (2010)
Solid-state dynamic nuclear polarization at 263 GHz: spectrometer design and experimental results.Physical chemistry chemical physics : PCCP, 12 22
J. Lang, D. Sloop, T. Lin (2007)
Dynamics of p-terphenyl crystals at the phase transition temperature: a zero-field EPR study of the photoexcited triplet state of pentacene in p-terphenyl crystals.The journal of physical chemistry. A, 111 22
T. Yago, J. Weidner, G. Link, T. Lin, G. Kothe (2007)
Quantum oscillations in photo-excited triplet states in an external magnetic fieldChemical Physics Letters, 438
J. K�hler, A. Brouwer, E. Groenen, J. Schmidt (1995)
Single Molecule Electron Paramagnetic Resonance Spectroscopy: Hyperfine Splitting Owing to a Single NucleusScience, 268
J. Woodward, †. Lin, A. Sakaguchi, H. Hayashi (2000)
Detection of Transient Intermediates in the Photochemical Reaction of Hydrogen Peroxide with Dimethyl sulfoxide by Time-Resolved EPR TechniquesJournal of Physical Chemistry A, 104
C. Felix, S. Weissman (1975)
Absence of interference in photoexcitation of triplets.Proceedings of the National Academy of Sciences of the United States of America, 72 11
C. Nonhof, F. Plantenga, Jan Schmidt, C. Varma, J. Waals (1979)
Intersystem crossing into a coherent superposition of spin states following flash excitationChemical Physics Letters, 60
T. Lin (1984)
Electron spin echo spectroscopy of organic tripletsChemical Reviews, 84
J. Baudour, H. Cailleau, W. Yelon (1977)
Structural phase transition in polyphenyls. IV. Double‐well potential in the disordered phase of p‐terphenyl from neutron (200 K) and X‐ray (room‐temperature) diffraction dataActa Crystallographica Section B Structural Crystallography and Crystal Chemistry, 33
Li-chung Yu, Gene-Hsiang Lee, M. Sigrist, T. Lin, S. Peng (2016)
Structure and Antiferromagnetism of Trinuclear Heterometallic Strings Containing MnII–MII–MnII Frameworks (M = Ni, Pd, Pt)European Journal of Inorganic Chemistry, 2016
T. Salaoru, J. Woodward (2007)
Rapid rise time pulsed magnetic field circuit for pump-probe field effect studies.The Review of scientific instruments, 78 3
D. Heuvel, A. Henstra, T. Lin, Jan Schmidt, W. Wenckebach (1992)
Transient oscillations in pulsed dynamic nuclear polarizationChemical Physics Letters, 188
Tran-chin Yang, D. Sloop, S. Weissman, T. Lin (2000)
Measurements of energy gap at the level anti-crossing region of the photo-excited triplet state of organic moleculesChemical Physics Letters, 331
A. Henstra, W. Wenckebach (2014)
Dynamic nuclear polarisation via the integrated solid effect I: theoryMolecular Physics, 112
A. Henstra, P. Dirksen, W. Wenckebach (1988)
Enhanced dynamic nuclear polarization by the integrated solid effectPhysics Letters A, 134
A. Pradhan, T. Lin, Wen-Hua Chen, S. Jong, Jin-Fu Wu, K. Chao, Shang-Bin Liu (1999)
EPR and NMR studies of coke induced selectivation over H-ZSM-5 zeolite during ethylbenzene disproportionation reactionJournal of Catalysis, 184
C. Cheng, T. Lin, D. Sloop (1976)
Electron spin-echo experiments of a ground organic triplet state in a single crystal, diphenylmethylene in benzophenoneChemical Physics Letters, 44
R. Hochstrasser (2006)
On a research rollercoaster with friends.Annual review of physical chemistry, 57
N. Gershenfeld, I. Chuang (1997)
Bulk Spin-Resonance Quantum ComputationScience, 275
J. Ong, D. Sloop, T. Lin (1995)
Deuteration effect on the spin dynamics of the photo-excited triplet state of pentacene in p-terphenyl crystalsChemical Physics Letters, 241
K. Takeda, K. Takegoshi, T. Terao (2001)
Dynamic nuclear polarization by photoexcited-triplet electron spins in polycrystalline samplesChemical Physics Letters, 345
D. Sloop, T. Lin, J. Ackerman (1999)
Transient magnetic resonance without RF pulses: fast field switching.Journal of magnetic resonance, 139 1
C. Zener (1932)
Non-Adiabatic Crossing of Energy LevelsProceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences, 137
G. Kothe, T. Yago, J. Weidner, Gerhard Link, M. Lukaschek, T. Lin (2010)
Quantum oscillations and polarization of nuclear spins in photoexcited triplet states.The journal of physical chemistry. B, 114 45
J. Woodward, T. Lin, Y. Sakaguchi, H. Hayashi (2000)
Application of benzophenones to elucidate the photochemical reaction pathways of hydrogen peroxide with dimethylsulfoxideApplied Magnetic Resonance, 18
P. Feng, Yi‐Hung Liu, T. Lin, S. Peng, Ching‐Wen Chiu (2014)
Redox chemistry of a hydroxyphenyl-substituted borane.Angewandte Chemie, 53 24
D. Sloop, Hsiang-Lin Yu, T. Lin, S. Weissman (1981)
Electron spin echoes of a photoexcited triplet: Pentacene in p‐terphenyl crystalsJournal of Chemical Physics, 75
Jan Schmidt, D. Heuvel, A. Henstra, T. Lin, W. Wenckebach (1992)
Polarizing Nuclear Spins Via Photo‐Excited Triplet StatesIsrael Journal of Chemistry, 32
C. Gemperle, A. Schweiger (1991)
PULSED ELECTRON-NUCLEAR DOUBLE RESONANCE METHODOLOGYChemical Reviews, 91
J. Colpa, D. Stehlik (1977)
Optical nuclear polarization as a consequence of the non-crossing rule (level-anti-crossing): I. Analytical treatment of ONP in the level-crossing region, 21
Hsiang-Lin Yu, T. Lin, D. Sloop (1983)
An electron spin echo study of the photoexcited triplet state of tetracene in p‐terphenyl crystals at room temperatureJournal of Chemical Physics, 78
R. Hochstrasser, T. Lin (1970)
Optical and Magnetic Field Studies of the Lowest Triplet State of the Pyrazine CrystalJournal of Chemical Physics, 53
K. Tateishi, M. Negoro, Shinsuke Nishida, A. Kagawa, Y. Morita, M. Kitagawa (2014)
Room temperature hyperpolarization of nuclear spins in bulkProceedings of the National Academy of Sciences, 111
J. Woodward, T. Lin, Y. Sakaguchi, H. Hayashi (2002)
Biphotonic photochemistry of benzophenones in dimethylsulphoxide: a flash photolysis EPR studyMolecular Physics, 100
V. Kouskov, D. Sloop, Shang-Bin Liu, T. Lin (1995)
Pulsed Transient Nutation Experiments of the Photo-Excited Triplet StateJournal of Magnetic Resonance, Series A, 117
V. Kouskov, D. Sloop, S. Weissman, T. Lin (1995)
Adiabatic passage through an avoided crossingChemical Physics Letters, 232
A. Karwa, A. Poreddy, B. Asmelash, T. Lin, R. Dorshow, R. Rajagopalan (2011)
Type 1 phototherapeutic agents, part I: preparation and cancer cell viability studies of novel photolabile sulfenamides.ACS medicinal chemistry letters, 2 11
Tran-chin Yang, D. Sloop, S. Weissman, T. Lin (2000)
Zero-field magnetic resonance of the photo-excited triplet state of pentacene at room temperatureJournal of Chemical Physics, 113
W. Mims (1972)
Electron Spin Echoes
Chia-Hung Lee, T. Lin, C. Mou (2009)
Mesoporous materials for encapsulating enzymesNano Today, 4
Jürgen Köhler, J. Disselhorst, M. Donckers, E. Groenen, Jan Schmidt, W. Moerner (1993)
Magnetic resonance of a single molecular spinNature, 363
Hsiang-Lin Yu, T. Lin, S. Weissman, D. Sloop (1984)
Time resolved studies of pentacene triplets by electron spin echo spectroscopyJournal of Chemical Physics, 80
J. Schmidt, D. Heuvel, A. Henstra, T.‐S. Lin, W. Wenckebach (1992)
Nuclear spin orientation via pulsed EPR and optically cooled triplet electron spinsPure and Applied Chemistry, 64
J. Lang, D. Sloop, T.‐S. Lin (2006)
Mapping the molecular axes of pentacene-d 14 doped in p-terphenyl single crystal using pulsed EPR technique in near zero magnetic fieldMolecular Physics, 104
L. Dugan, S. Sensi, LM Canzoniero, SD Handran, S. Rothman, Tsai-Shiuan Lin, M. Goldberg, D. Choi (1995)
Mitochondrial production of reactive oxygen species in cortical neurons following exposure to N-methyl-D-aspartate, 15
J. Lang, D. Sloop, T. Lin (2005)
Orientational anisotropic studies by field rotation technique: near zero-field pulsed EPR experiments of pentacene doped in p-terphenyl.Journal of magnetic resonance, 176 2
T. Lin, R. Rajagopalan, Yuefei Shen, Sungho Park, A. Poreddy, B. Asmelash, A. Karwa, John-Stephen Taylor (2013)
Roles of free radicals in type 1 phototherapeutic agents: aromatic amines, sulfenamides, and sulfenates.The journal of physical chemistry. A, 117 26
S. Bogatko, P. Haynes, Juna Sathian, Jessica Wade, Ji‐Seon Kim, K. Tan, J. Breeze, E. Salvadori, A. Horsfield, M. Oxborrow (2016)
Molecular Design of a Room-Temperature MaserJournal of Physical Chemistry C, 120
R. Hochstrasser, T. Lin (1969)
Zeeman effect of oriented molecules in solids at low temperaturesSymposia of The Faraday Society, 3
R. Hochstrasser, T. Lin, A. Zewail (1972)
Mixed Magnetic and Electric Dipole Transition in s‐TriazineJournal of Chemical Physics, 56
Shang-Bin Liu, T. Lin, Tran-chin Yang, Tung-ho Chen, E. Hong, R. Ryoo (1995)
EPR and 129Xe NMR Studies of Copper-Exchanged NaY Zeolites?The Journal of Physical Chemistry, 99
G. Kothe, M. Lukaschek, G. Link, S. Kacprzak, B. Illarionov, M. Fischer, W. Eisenreich, A. Bacher, S. Weber (2014)
Detecting a new source for photochemically induced dynamic nuclear polarization in the LOV2 domain of phototropin by magnetic-field dependent (13)C NMR spectroscopy.The journal of physical chemistry. B, 118 40
J. Ong, D. Sloop, T. Lin (1992)
Dynamics of the photoexcited triplet state of pentacene in an asymmetric double-well potential of p-terphenyl crystalsThe Journal of Physical Chemistry, 96
L. Vandersypen, Matthias Steffen, Gregory Breyta, C. Yannoni, Richard Cleve, I. State, P. Laboratory, Stanford Science, U. Calgary (2000)
Experimental realization of an order-finding algorithm with an NMR quantum computer.Physical review letters, 85 25
T. Lin, M. Bowman, J. Norris, G. Closs (1981)
Endor frequencies of randomly oriented triplets by electron spin echo spectroscopyChemical Physics Letters, 78
Iinuma, Takahashi, Shake, Oda, A Masaike, Yabuzaki, Shimizu (2000)
High proton polarization by microwave-induced optical nuclear polarization at 77 KPhysical review letters, 84 1
Chun-Chieh Wang, Hao‐Ching Chang, Yei-Chen Lai, Huayi Fang, Chieh-Chin Li, Hung-Kai Hsu, Zong-Yan Li, T. Lin, Ting‐Shen Kuo, F. Neese, Shengfa Ye, Y. Chiang, M. Tsai, W. Liaw, Way-Zen Lee (2016)
A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from Its Superoxo Intermediate via Hydrogen Atom Abstraction.Journal of the American Chemical Society, 138 43
J. Ong, D. Sloop, T. Lin (1994)
Peculiar spin dynamics of the photoexcited triplet state of pentacene in a benzoic acid crystal: an ESE studyApplied Magnetic Resonance, 6
D. Weitekamp, A. Bielecki, D. Zax, K. Zilm, A. Pines (1983)
Zero-field nuclear magnetic resonancePhysical Review Letters, 50
Hsiang-Lin Yu, D. Sloop, S. Weissman, T. Lin, J. Norris, M. Bowman (1982)
Electron spin echo modulation of the photoexcited triplets of anthracene in p-terphenyl crystalsThe Journal of Physical Chemistry, 86
We present a few novel pulsed electron paramagnetic resonance techniques developed in our laboratory for the studies of structure and dynamics of the photo‐excited triplet state of organic molecules. We discuss many aspects of these new techniques and the significances of these measurements: (1) enhancing NMR signal intensity by dynamic nuclear polarization ‐ integrated solid effect, (2) performing magnetic resonance in zero‐field and low‐field by pulsed microwave, (3) mapping molecular motion of organic crystals by pulsed zero‐field and low‐field experiments, (4) probing spin dynamics at level anti‐crossing by fast field switching, (5) measuring hyperfine interaction by electron spin echo envelop modulation and spin‐echo electron nuclear double resonance and (6) detecting spin dynamics, nuclear quantum oscillation, entanglements and new avenues for quantum computer. We have employed the highly electron spin polarized pentacene triplet state as the model system in all of our pulsed EPR experiments. We performed most of our experiments at room temperature. The goals of our studies are aiming to improve spin detectability, to probe molecular dynamics, to determine electronic structures, to measure molecular interaction and motion, and to examine quantum coherence and oscillation which may yield new avenues in the applications of pulsed EPR techniques to quantum computer.
Journal of the Chinese Chemical Society – Wiley
Published: Jan 1, 2018
Keywords: ; ; ;
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