Methane steam reforming, methanation and water‐gas shift: I. Intrinsic kinetics

Methane steam reforming, methanation and water‐gas shift: I. Intrinsic kinetics Intrinsic rate equations were derived for the steam reforming of methane, accompanied by water‐gas shift on a Ni/MgAl2O4 catalyst. A large number of detailed reaction mechanisms were considered. Thermodynamic analysis helped in reducing the number of possible mechanisms. Twenty one sets of three rate equations were retained and subjected to model discrimination and parameter estimation. The parameter estimates in the best model are statistically significant and thermodynamically consistent. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Aiche Journal Wiley

Methane steam reforming, methanation and water‐gas shift: I. Intrinsic kinetics

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Publisher
Wiley Subscription Services, Inc., A Wiley Company
Copyright
Copyright © 1989 American Institute of Chemical Engineers
ISSN
0001-1541
eISSN
1547-5905
D.O.I.
10.1002/aic.690350109
Publisher site
See Article on Publisher Site

Abstract

Intrinsic rate equations were derived for the steam reforming of methane, accompanied by water‐gas shift on a Ni/MgAl2O4 catalyst. A large number of detailed reaction mechanisms were considered. Thermodynamic analysis helped in reducing the number of possible mechanisms. Twenty one sets of three rate equations were retained and subjected to model discrimination and parameter estimation. The parameter estimates in the best model are statistically significant and thermodynamically consistent.

Journal

Aiche JournalWiley

Published: Jan 1, 1989

References

  • Kinetics of the Methane‐Steam Reaction
    Akers, Akers; Camp, Camp

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