Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Ionic‐Liquid‐Based Synthesis of the Bromine‐Rich Bromidoplatinates [NBu3Me]2[Pt2Br10](Br2)2 and [NBu3Me]2[Pt2Br10](Br2)3

Ionic‐Liquid‐Based Synthesis of the Bromine‐Rich Bromidoplatinates [NBu3Me]2[Pt2Br10](Br2)2 and... The bromine‐rich bromidoplatinates(IV) [NBu3Me]2[Pt2Br10](Br2)2 (1) and [NBu3Me]2[Pt2Br10](Br2)3 (2) were prepared by reaction of PtBr4 and elemental bromine in the ionic liquid [MeBu3N][N(Tf)2] [N(Tf)2 = bis(trifluoromethylsulfonyl)amide]. Both bromine‐rich bromidoplatinates(IV) contain [Pt2Br10]2– anions and [NBu3Me]+ cations as voluminous building units with an almost identical structural arrangement and very similar unit cells. The difference of the title compounds is related to the specific number of Br2 molecules that link the [Pt2Br10]2– anions to three‐dimensional networks. Whereas 1 is relatively stable under inert conditions, 2 releases bromine even at ambient pressure. The title compounds are characterized by single‐crystal structure analysis and Raman spectroscopy. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für anorganische und allgemeine Chemie Wiley

Ionic‐Liquid‐Based Synthesis of the Bromine‐Rich Bromidoplatinates [NBu3Me]2[Pt2Br10](Br2)2 and [NBu3Me]2[Pt2Br10](Br2)3

Loading next page...
 
/lp/wiley/ionic-liquid-based-synthesis-of-the-bromine-rich-bromidoplatinates-JFVxZ1nyag

References (27)

Publisher
Wiley
Copyright
"© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim"
ISSN
0044-2313
eISSN
1521-3749
DOI
10.1002/zaac.201700409
Publisher site
See Article on Publisher Site

Abstract

The bromine‐rich bromidoplatinates(IV) [NBu3Me]2[Pt2Br10](Br2)2 (1) and [NBu3Me]2[Pt2Br10](Br2)3 (2) were prepared by reaction of PtBr4 and elemental bromine in the ionic liquid [MeBu3N][N(Tf)2] [N(Tf)2 = bis(trifluoromethylsulfonyl)amide]. Both bromine‐rich bromidoplatinates(IV) contain [Pt2Br10]2– anions and [NBu3Me]+ cations as voluminous building units with an almost identical structural arrangement and very similar unit cells. The difference of the title compounds is related to the specific number of Br2 molecules that link the [Pt2Br10]2– anions to three‐dimensional networks. Whereas 1 is relatively stable under inert conditions, 2 releases bromine even at ambient pressure. The title compounds are characterized by single‐crystal structure analysis and Raman spectroscopy.

Journal

Zeitschrift für anorganische und allgemeine ChemieWiley

Published: Mar 15, 2019

Keywords: ; ; ; ;

There are no references for this article.