Improved Performance of Printable Perovskite Solar Cells with Bifunctional Conjugated Organic Molecule

Improved Performance of Printable Perovskite Solar Cells with Bifunctional Conjugated Organic... A bifunctional conjugated organic molecule 4‐(aminomethyl) benzoic acid hydroiodide (AB) is designed and employed as an organic cation in organic–inorganic halide perovskite materials. Compared with the monofunctional cation benzylamine hydroiodide (BA) and the nonconjugated bifunctional organic molecule 5‐ammonium valeric acid, devices based on AB‐MAPbI3 show a good stability and a superior power conversion efficiency of 15.6% with a short‐circuit current of 23.4 mA cm−2, an open‐circuit voltage of 0.94 V, and a fill factor of 0.71. The bifunctional conjugated cation not only benefits the growth of perovskite crystals in the mesoporous network, but also facilitates the charge transport. This investigation helps explore new approaches to rational design of novel organic cations for perovskite materials. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Advanced Materials Wiley

Improved Performance of Printable Perovskite Solar Cells with Bifunctional Conjugated Organic Molecule

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Publisher
Wiley Subscription Services, Inc., A Wiley Company
Copyright
© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
0935-9648
eISSN
1521-4095
D.O.I.
10.1002/adma.201705786
Publisher site
See Article on Publisher Site

Abstract

A bifunctional conjugated organic molecule 4‐(aminomethyl) benzoic acid hydroiodide (AB) is designed and employed as an organic cation in organic–inorganic halide perovskite materials. Compared with the monofunctional cation benzylamine hydroiodide (BA) and the nonconjugated bifunctional organic molecule 5‐ammonium valeric acid, devices based on AB‐MAPbI3 show a good stability and a superior power conversion efficiency of 15.6% with a short‐circuit current of 23.4 mA cm−2, an open‐circuit voltage of 0.94 V, and a fill factor of 0.71. The bifunctional conjugated cation not only benefits the growth of perovskite crystals in the mesoporous network, but also facilitates the charge transport. This investigation helps explore new approaches to rational design of novel organic cations for perovskite materials.

Journal

Advanced MaterialsWiley

Published: Jan 1, 2018

Keywords: ; ; ; ;

References

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