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Bi2O3 nanostructures with high surface‐to‐volume ratio are attracting particular interest in catalysis, gas sensors, solar‐energy conversion, and so on. In this paper, we present the impact of annealing on morphology, structure, and optical properties of Bi2O3 nanotube‐based urchin‐like microarchitectures, which is very important to determine before their applications in many potential fields. Our results showed that below 400 °C, the microarchitectures possessed good thermal stability. While annealing at 500 °C, jointed nanoparticles with an average size of 350 nm were formed. On further increasing the annealing temperature to 600 °C, the microarchitectures were transformed into stable α‐Bi2O3 microcrystal film with a larger particle size of about 800 nm. The optical bandgaps of the annealed products were also changed according to their changes of morphology and structure.
Physica Status Solidi (A) Applications and Materials Science – Wiley
Published: Nov 1, 2012
Keywords: ; ; ; ;
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