Identification of relaxation processes in pure polyethylene oxide (PEO) films by the dielectric permittivity and electric modulus formalisms

Identification of relaxation processes in pure polyethylene oxide (PEO) films by the dielectric... The ac‐impedance of bulk‐like films of pure polyethylene oxide (PEO) polymer was measured as a function of frequency f in the range 0.1 to 107 Hz at various constant temperatures T (155 − 330 K). The as‐measured data were analyzed by electric permittivity and modulus formalisms to unveil which dielectric and conductive relaxation processes were responsible for their relaxation behavior below/above glass transition temperature Tg of pure PEO polymer. At T > Tg, none of the α‐, β‐, or γ‐relaxations could be inferred for studied pure PEO films from frequency variation of measured imaginary part ε′′(f, T) of complex dielectric permittivity ε~fT, as low‐frequency losses masked real dielectric contribution to the measured ε′′(f, T) at low frequencies and high temperatures. However, at T < Tg, a broad, relaxation process has been observed in the high‐frequency part of their isothermal ε′′(f, T) − f spectra, which can be related to the β‐ or γ‐dielectric relaxation process. Nonlinear regressions of the measured ε′′(f, T) − f data for T < Tg yielded moral fits to a simple addition of a Havriliak‐Negami function, and a Bergman‐loss Kohlrausch‐Williams‐Watts‐type function, with the relaxation time τmax(T) obtained from Havriliak‐Negami‐fitting parameters, was found to follow a thermally activated Arrhenius‐like relaxation behavior. Conversely, representation of the imaginary part M′′(f, T > Tg) − f spectra of complex electric modulus M~f=1/ε~f was found to depict 2 overlapped relaxation processes, which were detached well by a nonlinear regression of a simple superposition of 2 different M′′(f) expressions having the form of the universal Bergman loss function, where it was found that the relaxation time is also thermally activated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Polymers for Advanced Technologies Wiley

Identification of relaxation processes in pure polyethylene oxide (PEO) films by the dielectric permittivity and electric modulus formalisms

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Publisher
Wiley
Copyright
Copyright © 2018 John Wiley & Sons, Ltd.
ISSN
1042-7147
eISSN
1099-1581
DOI
10.1002/pat.4306
Publisher site
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Abstract

The ac‐impedance of bulk‐like films of pure polyethylene oxide (PEO) polymer was measured as a function of frequency f in the range 0.1 to 107 Hz at various constant temperatures T (155 − 330 K). The as‐measured data were analyzed by electric permittivity and modulus formalisms to unveil which dielectric and conductive relaxation processes were responsible for their relaxation behavior below/above glass transition temperature Tg of pure PEO polymer. At T > Tg, none of the α‐, β‐, or γ‐relaxations could be inferred for studied pure PEO films from frequency variation of measured imaginary part ε′′(f, T) of complex dielectric permittivity ε~fT, as low‐frequency losses masked real dielectric contribution to the measured ε′′(f, T) at low frequencies and high temperatures. However, at T < Tg, a broad, relaxation process has been observed in the high‐frequency part of their isothermal ε′′(f, T) − f spectra, which can be related to the β‐ or γ‐dielectric relaxation process. Nonlinear regressions of the measured ε′′(f, T) − f data for T < Tg yielded moral fits to a simple addition of a Havriliak‐Negami function, and a Bergman‐loss Kohlrausch‐Williams‐Watts‐type function, with the relaxation time τmax(T) obtained from Havriliak‐Negami‐fitting parameters, was found to follow a thermally activated Arrhenius‐like relaxation behavior. Conversely, representation of the imaginary part M′′(f, T > Tg) − f spectra of complex electric modulus M~f=1/ε~f was found to depict 2 overlapped relaxation processes, which were detached well by a nonlinear regression of a simple superposition of 2 different M′′(f) expressions having the form of the universal Bergman loss function, where it was found that the relaxation time is also thermally activated.

Journal

Polymers for Advanced Technologies – Wiley

Published: Jan 1, 2018

Keywords: ; ; ;

References

  • Poly(ethylene oxide)‐based electrolytes for lithium‐ion batteries
    Xue, Z; He, D; Xie, X
  • Polymer electrolytes: Present, past and future
    Di Noto, V; Lavina, S; Giffin, GA; Negro, E; Scrosati, B
  • Solid Polymer Electrolytes—Fundamentals and Technological Applications
    Gray, FM
  • An overview of the research and development of solid polymer electrolyte batteries
    Murata, K; Izuchi, S; Yoshihisa, Y
  • Issues and challenges facing rechargeable lithium batteries
    Tarascon, JM; Armand, M
  • Electrolytes for solid‐state lithium rechargeable batteries: Recent advances and perspectives
    Quartarone, E; Mustarelli, P
  • Charge carrier dynamics and relaxation in (polyethylene‐oxide‐lithium‐salt)‐based polymer electrolyte containing 1‐butyl‐1methylpyrrolidinium bis (trifluoromethylsulfonyl) imide as ionic liquid
    Karmakar, A; Ghosh, A
  • Effect of plasticizers on ionic conductivity and dielectric relaxation of PEO‐LiClO4 polymer electrolyte
    Das, S; Ghosh, A
  • Ionic relaxation in PEO/PVDE‐HFP‐LiClO4 blend polymer electrolytes
    Das, S; Ghosh, A
  • Structure, ion transport, and relaxation dynamics of polyethylene oxide/poly (vinylidene fluoride co‐hexafluoropropylene)‐lithium bis (trifluoromethane sulfonyl) imide blend polymer electrolyte embedded with ionic liquid
    Das, S; Ghosh, A
  • Glass transitions of ethylene oxide polymers
    Faucher, JA; Koleske, JV; Santee, ER; Stratta, JJ; Wilson, CW
  • Chain dynamics and viscoelastic properties of ply(ethylene oxide)
    Niedzwiedz, K; Wishnewski, A; Pyckhout‐Hintzen, W; Allgaier, J; Richter, D; Faraone, A
  • Simulated glass transition of poly(ethylene oxide) bulk and film: a comparative study
    Wu, C
  • Salt‐concentration dependence of the glass transition temperature in PEO‐NaI and PEO‐LiTFSI polymer electrolytes
    Stolwijk, NA; Heddier, C; Reschke, M; Wiencierz, M; Bokeloh, J; Wilde, G
  • A dielectric relaxation study of nanocomposite polymer electrolytes
    Money, BK; Hariharan, K; Swenson, J
  • Composite polymer electrolytes: nanoparticles affect structure and properties
    Wang, W; Alexandridis, P
  • Solvent cast technology—a versatile tool for thin film production
    Siemann, U
  • Optical Properties of Iodine‐Doped‐Poly(Ethylene Oxide)
    Al‐Khalayleh, BM
  • Ultrathin films of poly(ethylene oxides) on oxidized silicon. 1. Spectroscopic characterization of film structure and crystallization kinetics
    Schönherr, H; Frank, CW
  • Relationship between morphological change and crystalline phase transitions of polyethylene‐poly(ethylene oxide) diblock copolymers. 3. Dependence of morphological transition phenomena on the PE/PEO segmental lengths and its possible origins
    Cao, W; Tashiro, K; Masunaga, H; Sasaki, S; Takata, M
  • Spherulite crystallization in poly(ethylene oxide)‐silica nanocomposites: retardation of growth rates through reduced molecular mobility
    Waddon, AJ; Petrovic, ZS
  • Efficiency enhancement by mixed cation effect in polyethylene oxide OEO‐based dye‐sensitized solar cells
    Dissanayake, MAKL; Ekanayake, EMBS; Bandara, LRAK
  • Dynamics of poly(ethylene oxide) around its melting temperature
    Money, BK; Swenson, J
  • Glass transition processes of nanocomposite polymer electrolytes
    Money, BK; Hariharan, K; Swenson, J
  • Relation between structural and conductivity relaxation in PEO and PEO based electrolytes
    Money, BK; Hariharan, K; Swenson, J
  • Observations of a fast dielectric relaxation in semi‐crystalline poly(ethylene oxide)
    Jin, X; Zhang, S; Runt, J
  • Study of the electrical conduction in poly(ethylene oxide) doped with iodine
    Abu‐Jamous, A; Zihlif, AM
  • Anisotropic ion transport in a poly(ethylene oxide)‐LiClO4 solid state electrolyte templated by graphene oxide
    Cheng, S; Smith, DM; Li, CY
  • Enhancing the ionic conductivity of PEO based plasticized composite polymer electrolyte by LaMnO3 nanofiller
    Kuila, T; Acharya, H; Srivastava, SK; Samantaray, BK; Kureti, S
  • Electronic processes in non‐crystalline materials
    Mott, NF; Davis, EA
  • Dielectric Relaxation in Solids
    Jonscher, AK
  • Impedance Spectroscopy
    Macdonald, JR
  • Broad Dielectric Spectroscopy
    Kremer, F; Schönhals, A
  • Electrical pProperties of Polymers
    Riande, E; Diaz‐Calleja, R
  • Methods to study the ionic conductivity of polymeric electrolytes using ac‐impedance spectroscopy
    Qian, X; Gu, N; Cheng, Z; Yang, X; Wang, E; Dong, S
  • Conductivity in disoprdered structures: verification of the generalized Jonscher's law on experimental data
    Popov, II; Nigmatullin, RR; Khazmin, AA; Lounev, IV
  • The generalized Jonscher's relationship for conductivity and its confirmation for porous structures
    Popov, II; Nigmatullin, RR; Yu, KE; Nabereznov, AA
  • Correction of the power law of ac conductivity in ion‐conducting materials due to the electrode polarization effect
    Khazmin, AA; Popov, II; Nigmatullin, RR
  • Non‐Debye dielectric relaxation in complex materials
    Feldman, Y; Puzenko, A; Ryabov, Y
  • Dielectric spectroscopy data treatment: I. Frequency domain
    Axelrod, N; Axelrod, E; Gutina, A; Puzenko, A; Ben, IP; Feldman, Y
  • Analysis of complex dielectric spectra. I. One‐dimensional derivative techniques and three‐dimensional modelling
    Wübbenhorst, M; Turnhout, J
  • Analysis for a dipolar relaxation in the featureless dielectric spectrum, and a comparison between the permittivity, modulus and impedance representations
    Parthun, M; Johari, GP
  • Comments on the electric modulus function
    Hodge, IM; Ngai, KL; Moynihan, CT
  • Dielectric and conductivity relaxation in poly(3,4‐ethylenedioxythiophene) nanotubes
    Chutia, P; Kumar, A
  • Electric modulus and interfacial polarization in composite polymeric systems
    Tsangaris, GM; Psarras, GC; Kouloumbi, N
  • Dielectric Relaxation Spectroscopy for Polymer Nanocomposites in Characterization Techniques for Polymer Nanocomposites
    Chanmal, C; Jog, J
  • An electrical circuit model of the alpha‐beta merging seen in dielectric of ultraviscous liquids
    Saǧlanmak, N.; Nielsen, A. I.; Olsen, N. B.; Dyre, J. C.; Niss, K.
  • Comment on the maximum in the loss permittivity for the Havriliak‐Negami equation
    Diaz‐Calleja, R
  • Comments on the electric modulus formalism model and superior alternatives to it for the analysis of the frequency response of ionic conductors
    Macdonald, JR
  • Relationship between the time‐domain Kohlrausch‐Williams‐Watts and frequency‐domain Havriliak‐Negami relation functions
    Alvarez, F; Alegría, A; Colmenero, J
  • Impedance spectroscopy: models, data fitting, and analysis
    Macdonald, JR
  • General susceptibility functions for relaxations in disordered systems
    Bergman, R
  • The merging of the dielectric α‐ and β‐relaxations in poly‐(methyl methacrylate)
    Bergman, R; Alvarez, F; Colmenero, J
  • Why C1=16–17 in the WLF equation is physical—and the fragility of polymers
    Angell, CA
  • Dielectric and conduction mechanisms of parylene N at high temperature: phase‐transition effect
    Kachroudi, A; Kahouli, A; Legrand, J; Jomni, F
  • Glassy dynamics in mono‐, di‐ and tri‐propylene glycol: From the α‐ to the fast β‐relaxation
    Kohler, M; Lunkenheimer, P; Goncharov, Y; When, R; Loidl, A
  • Relationship between the primary and secondary dielectric relaxation processes in propylene glycol and its oligomers
    León, C; Ngai, L; Roland, CM

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