7/17 Pages 3625 ± 3846 COVER PICTURE The cover picture shows the potential energy surface (PES) of the gold triiodide molecule (AuI ) with a novel L-shaped structure in the minimum energy position. A variety of the molecular orbitals for gold triiodides are shown in the background. It has been known that gold trihalides are not stable in their most symmetrical trigonal planar coordination, because they are subject to the Jahn ± Teller effect and distort to lower symmetry T- or Y-shaped structures (also depicted on the PES). Our study revealed that this behavior depends on the halogen ligands, and that it changes gradually from the fluoride to the iodide. The structures and stabilities of the gold trihalides, together with those of the gold monohalides and all their dimers, are described in detail by M. Hargittai and A. Schulz on p. 3657 ff. Contents CONCEPTS The controlled formation of synthetic molecular G. F. Swiegers,* containers by metal-mediated self-assembly is an T. J. Malefetse .............. 3636 ± 3643 increasingly important field because of the multi- faceted chemistry that can often be performed Classification of Coordination Polygons within such containers (see figure). This work and Polyhedra According to Their Mode proposes
Chemistry - A European Journal – Wiley
Published: Mar 3, 2001
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera