Graphene‐Based Carbocatalysts for Thermoset Polymers and for Diastereoselective and Enantioselective Organic Synthesis

Graphene‐Based Carbocatalysts for Thermoset Polymers and for Diastereoselective and... This review reports on the catalytic activity of graphene oxide (GO) and high‐surface‐area graphite (HSAG) for some relevant organic reactions. It is shown that the main drawbacks of graphite‐based catalysts, that is, high catalyst loading and generally poor selectivity, can often be removed by operating under solvent‐free conditions. Moreover, some reactions that are catalyzed by GO as well as HSAG are presented. For these reactions, π stacking of the aromatic substrates with the graphitic planes plays a predominant role in the catalytic activity and the unexpected diastereoselective and enantioselective behaviors. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemCatChem (Electronic) Wiley

Graphene‐Based Carbocatalysts for Thermoset Polymers and for Diastereoselective and Enantioselective Organic Synthesis

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Publisher
Wiley Subscription Services, Inc., A Wiley Company
Copyright
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1867-3880
eISSN
1867-3899
D.O.I.
10.1002/cctc.201702015
Publisher site
See Article on Publisher Site

Abstract

This review reports on the catalytic activity of graphene oxide (GO) and high‐surface‐area graphite (HSAG) for some relevant organic reactions. It is shown that the main drawbacks of graphite‐based catalysts, that is, high catalyst loading and generally poor selectivity, can often be removed by operating under solvent‐free conditions. Moreover, some reactions that are catalyzed by GO as well as HSAG are presented. For these reactions, π stacking of the aromatic substrates with the graphitic planes plays a predominant role in the catalytic activity and the unexpected diastereoselective and enantioselective behaviors.

Journal

ChemCatChem (Electronic)Wiley

Published: Jan 7, 2018

Keywords: ; ; ; ;

References

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