Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/enzymatic-preparation-of-biosurfactants-from-sugars-or-sugar-alcohols-bBh8qCU10r
References (23)
-
R. Lortie, M. Trani, F. Ergan (1993)
Kinetic study of the lipase‐catalyzed synthesis of trioleinBiotechnology and Bioengineering, 41
-
F. Björkling, S. Godtfredsen, O. Kirk (1989)
A highly selective enzyme-catalysed esterification of simple glucosidesJournal of The Chemical Society, Chemical Communications
-
K. Adelhorst, F. Bjoerkling, S. Godtfredsen, O. Kirk (1990)
Enzyme Catalyzed Preparation of 6‐O‐Acylglucopyranosides.ChemInform, 21
-
M. Thérisod, A. Klibanov (1986)
Facile enzymatic preparation of monoacylated sugars in pyridineJournal of the American Chemical Society, 108
-
G. Fregapane, D. Sarney, E. Vulfson (1991)
Enzymic solvent-free synthesis of sugar acetal fatty acid estersEnzyme and Microbial Technology, 13
-
(1994)
Enzymatic synthesis of carbohydrate esters. Carbohydrates polyesters as fat substitutes. Food science and technology: A series of monographs, textbooks, and references -
(1986)
Enzymes that work in organic solvents -
Y. Dudal, R. Lortie (1995)
Influence of water activity on the synthesis of triolein catalyzed by immobilized Mucor miehei lipaseBiotechnology and Bioengineering, 45
-
L. Guillardeau, D. Montēt, N. Khaled, M. Pina, J. Graille (1992)
Fructose Caprylate Biosynthesis in a Solvent-free MediumTenside Surfactants Detergents, 29
-
H. Seino, T. Uchibori, Toshiyuki Nishitani, S. Inamasu (1984)
Enzymatic synthesis of carbohydrate esters of fatty acid (I) esterification of sucrose, glucose, fructose and sorbitolJournal of the American Oil Chemists’ Society, 61
-
S. Bloomer, P. Adlercreutz, B. Mattiasson (1991)
Triglyceride Interesterification by Lipases: 2. Reaction parameters for the reduction of trisaturated impurities and diglycerides in batch reactionsBiocatalysis and Biotransformation, 5
-
S. Riva, J. Chopineau, A. Kieboom, A. Klibanov (1988)
Protease-catalyzed regioselective esterification of sugars and related compounds in anhydrous dimethylformamideJournal of the American Chemical Society, 110
-
H. Maag (1984)
Fatty acid derivatives: Important surfactants for household, cosmetic and industrial purposesJournal of the American Oil Chemists’ Society, 61
-
F. Ergan, M. Trani, G. André (1990)
Production of glycerides from glycerol and fatty acid by immobilized lipases in non‐aqueous mediaBiotechnology and Bioengineering, 35
-
L. Mutua, C. Akoh (1993)
Synthesis of alkyl glycoside fatty acid esters in non-aqueous media byCandida sp. lipaseJournal of the American Oil Chemists’ Society, 70
-
(1992)
Facile esterification of fatty acid esters in high yields -
J. Fabre, D. Betbeder, F. Paul, P. Monsan, J. Périé (1993)
Regiospecific enzymic acylation of butyl α-d-glucopyranosideCarbohydrate Research, 243
-
K. Yoshimoto, Y. Itatani, Y. Tsuda (1980)
^ C-Nuclear Magnetic Resonance (NMR) Spectra of O-Acylglucoses. Additivity of Shift Parameters and Its Application to Structure ElucidationsChemical & Pharmaceutical Bulletin, 28
-
P. Halling (1994)
Thermodynamic predictions for biocatalysis in nonconventional media: theory, tests, and recommendations for experimental design and analysis.Enzyme and microbial technology, 16 3
-
W. Griffin (1946)
Classification of surface-active agents by "HLB", 1
-
J. Chopineau, Frank McCafferty, M. Thérisod, A. Klibanov (1988)
Production of biosurfactants from sugar alcohols and vegetable oils catalyzed by lipases in a nonaqueous mediumBiotechnology and Bioengineering, 31
-
A. Janssen, N. Boer, K. Riet (1993)
Solvent effects on the equilibrium position of lipase-catalyzed esterification of decanoic acid and various alcohols., 8
-
R. Khan (1976)
The Chemistry of SucroseAdvances in Carbohydrate Chemistry and Biochemistry, 33
- Publisher
- Wiley
- Copyright
- Copyright © 1995 John Wiley & Sons, Inc.
- ISSN
- 0006-3592
- eISSN
- 1097-0290
- DOI
- 10.1002/bit.260480308
- pmid
- 18623481
- Publisher site
- See Article on Publisher Site
Abstract
10.1002/bit.260480308.abs Biosurfactants were prepared by enzymatic esterification of sugars and sugar alcohols in nonaqueous media. Sorbitol monooleate was produced in pure molten substrates, with reduced pressure to remove water. The results were compared to synthesis in organic solvent, with and without water removal. Synthesis in organic solvent with water removal, obtained by refluxing through a desiccant under reduced pressure, proved to be the most efficient method in terms of total yield and side‐products formation. This process was applied to the production of different surfactants, by changing the nature of the hydrophilic and hydrophobic moieties. Yields above 90% of monoesters were obtained after 24 h when the reaction was carried out in 2‐methyl‐2‐butanol with Novozym 435 (Type B lipase from Candida antarctica) with an excess of hydroxyl donor. © 1995 John Wiley & Sons, Inc.
Journal
Biotechnology and Bioengineering – Wiley
Published: Nov 5, 1995