Access the full text.
Sign up today, get DeepDyve free for 14 days.
Kebin Zhou, Xun Wang, Xiaoming Sun, Q. Peng, Yadong Li (2005)
Enhanced catalytic activity of ceria nanorods from well-defined reactive crystal planesJournal of Catalysis, 229
Nguyen Long, M. Ohtaki, M. Nogami, T. Hien (2011)
Effects of heat treatment and poly(vinylpyrrolidone) (PVP) polymer on electrocatalytic activity of polyhedral Pt nanoparticles towards their methanol oxidationColloid and Polymer Science, 289
Yuen Wu, Dingsheng Wang, Yadong Li (2014)
Nanocrystals from solutions: catalysts.Chemical Society reviews, 43 7
Xiong Liu, M. Atwater, Jinhai Wang, Q. Dai, J. Zou, J. Brennan, Q. Huo (2007)
A study on gold nanoparticle synthesis using oleylamine as both reducing agent and protecting ligand.Journal of nanoscience and nanotechnology, 7 9
L. Altmann, Xiaodong Wang, J. Stöver, M. Klink, V. Zielasek, K. Thiel, J. Kolny-Olesiak, K. Al‐Shamery, H. Borchert, J. Parisi, M. Bäumer (2013)
Impact of Organic Ligands on the Structure and Hydrogenation Performance of Colloidally Prepared Bimetallic PtSn NanoparticlesChemCatChem, 5
Patrick Sonström, D. Arndt, Xiaodong Wang, Volkmar Zielasek, M. Bäumer (2011)
Kolloidchemisch hergestellte ligandenstabilisierte Nanopartikel – ein Weg zur Beeinflussung starker Metall-Träger-Wechselwirkungen in der heterogenen Gasphasenkatalyse†Angewandte Chemie, 123
W. Liu, Hailiang Wang (2016)
Influence of surface capping on oxygen reduction catalysis: A case study of 1.7 nm Pt nanoparticlesSurface Science, 648
Yuan Wang, Jiawen Ren, Kai Deng, and Gui, Youqi Tang (2000)
Preparation of Tractable Platinum, Rhodium, and Ruthenium Nanoclusters with Small Particle Size in Organic MediaChemistry of Materials, 12
Bojun Zuo, Y. Wang, Qilong Wang, Junling Zhang, N. Wu, Lidan Peng, L. Gui, Xiaodong Wang, Rongming Wang, D. Yu (2004)
An efficient ruthenium catalyst for selective hydrogenation of ortho-chloronitrobenzene prepared via assembling ruthenium and tin oxide nanoparticlesJournal of Catalysis, 222
Zhihuan Weng, F. Zaera (2014)
Increase in Activity and Selectivity in Catalysis via Surface Modification with Self-Assembled MonolayersJournal of Physical Chemistry C, 118
J. Serrano-Ruiz, Ana López-Cudero, J. Solla-Gullón, A. Sepúlveda-Escribano, A. Aldaz, F. Rodríguez-Reinoso (2008)
Hydrogenation of α, β unsaturated aldehydes over polycrystalline, (111) and (100) preferentially oriented Pt nanoparticles supported on carbonJournal of Catalysis, 253
S. Kunz, E. Iglesia (2014)
Mechanistic Evidence for Sequential Displacement–Reduction Routes in the Synthesis of Pd–Au Clusters with Uniform Size and Clean SurfacesJournal of Physical Chemistry C, 118
Tianyou Chen, V. Rodionov (2016)
Controllable Catalysis with Nanoparticles: Bimetallic Alloy Systems and Surface AdsorbatesACS Catalysis, 6
Revised manuscript received
Chaoliang Tan, Hua Zhang (2015)
Wet-chemical synthesis and applications of non-layer structured two-dimensional nanomaterialsNature Communications, 6
Linwei Zhang, A. Gao, Yan Liu, Yuanyuan Wang, Jiantai Ma (2014)
PtRu nanoparticles dispersed on nitrogen-doped carbon nanohorns as an efficient electrocatalyst for methanol oxidation reactionElectrochimica Acta, 132
S. Campisi, Marco Schiavoni, C. Chan-Thaw, A. Villa (2016)
Untangling the Role of the Capping Agent in Nanocatalysis: Recent Advances and PerspectivesCatalysts, 6
Xiaoyi Fu, Yuan Wang, N. Wu, L. Gui, Youqi Tang (2001)
Surface modification of small platinum nanoclusters with alkylamine and alkylthiol: An XPS study on the influence of organic ligands on the Pt 4f binding energies of small platinum nanoclustersJournal of Colloid and Interface Science, 243
Xiaodong Wang, P. Sonstroem, D. Arndt, J. Stöver, V. Zielasek, H. Borchert, K. Thiel, K. Al‐Shamery, M. Bäumer (2011)
Heterogeneous catalysis with supported platinum colloids: A systematic study of the interplay between support and functional ligandsJournal of Catalysis, 278
Zhiqiang Niu, Yadong Li (2014)
Removal and Utilization of Capping Agents in NanocatalysisChemistry of Materials, 26
Jeremy Smith, P. Jain (2016)
The Ligand Shell as an Energy Barrier in Surface Reactions on Transition Metal Nanoparticles.Journal of the American Chemical Society, 138 21
D. Fenske, P. Sonstroem, J. Stöver, Xiaodong Wang, H. Borchert, J. Parisi, J. Kolny-Olesiak, M. Bäumer, K. Al‐Shamery (2010)
Colloidally Prepared Pt Nanoparticles for Heterogeneous Gas‐Phase Catalysis: Influence of Ligand Shell and Catalyst Loading on CO Oxidation ActivityChemCatChem, 2
Chao Xiao, Xiaodong Wang, Chao Lian, Hong-qiang Liu, Minghui Liang, Y. Wang (2012)
Selective Hydrogenation of HalonitrobenzenesChemInform, 43
R. Khomane, A. Manna, A. Mandale, B. Kulkarni (2002)
Synthesis and characterization of dodecanethiol-capped cadmium sulfide nanoparticles in a winsor II microemulsion of diethyl ether/AOT/waterLangmuir, 18
B. Coq, A. Tijani, F. Figuéras (1992)
Influence of alloying platinum for the hydrogenation of p-chloronitrobenzene over PtM/Al2O3 catalysts with MSn, Pb, Ge, Al, ZnJournal of Molecular Catalysis, 71
Pengxin Liu, R. Qin, G. Fu, N. Zheng (2017)
Surface Coordination Chemistry of Metal Nanomaterials.Journal of the American Chemical Society, 139 6
(1984)
Strätz in Catalysis of Organic Reactions
Ruyi Zhong, Keqiang Sun, Yongchun Hong, Bo-Qing Xu (2014)
Impacts of Organic Stabilizers on Catalysis of Au Nanoparticles from Colloidal PreparationACS Catalysis, 4
Y. Wan, Haifeng Yang, Dongyuan Zhao (2006)
"Host-guest" chemistry in the synthesis of ordered nonsiliceous mesoporous materials.Accounts of chemical research, 39 7
(2009)
Angew.C hem. Int
P. Sonstroem, M. Bäumer (2011)
Supported colloidal nanoparticles in heterogeneous gas phase catalysis: on the way to tailored catalysts.Physical chemistry chemical physics : PCCP, 13 43
Qiong Xu, Xinmiao Liu, Junru Chen, Ruixiang Li, Xian-jun Li (2006)
Modification mechanism of Sn4+ for hydrogenation of p-chloronitrobenzene over PVP-Pd/γ-Al2O3Journal of Molecular Catalysis A-chemical, 260
D. Bazin, D. Sayers, J. Rehr, C. Mottet (1997)
Numerical Simulation of the Platinum LIII Edge White Line Relative to Nanometer Scale ClustersJournal of Physical Chemistry B, 101
Younan Xia, Yujie Xiong, Byungkwon Lim, Sara Skrabalak (2009)
Formkontrolle bei der Synthese von Metallnanokristallen: einfache Chemie, komplexe Physik?Angewandte Chemie, 121
Chao Lian, Xiaoling Xiao, Zheng Chen, Yuxi Liu, Enyue Zhao, Dingsheng Wang, Chen Chen (2016)
Preparation of hexagonal ultrathin WO3 nano-ribbons and their electrochemical performance as an anode material in lithium ion batteriesNano Research, 9
S. Kunz, Mark Maturi, I. Schrader, Jana Backenköhler, M. Tschurl, U. Heiz (2014)
Same ligand--different binding: a way to control the binding of N-acetyl-cysteine (NAC) to Pt clusters.Journal of colloid and interface science, 426
J. Kuhn (2009)
Effect of Organic Capping Layers over Monodisperse Platinum Nanoparticles upon Activity for Ethylene Hydrogenation and Carbon Monoxide OxidationLawrence Berkeley National Laboratory
V. Ho, Chun-Jern Pan, J. Rick, Wei‐Nien Su, B. Hwang (2011)
Nanostructured Ti(0.7)Mo(0.3)O2 support enhances electron transfer to Pt: high-performance catalyst for oxygen reduction reaction.Journal of the American Chemical Society, 133 30
I. Schrader, J. Warneke, Jana Backenköhler, S. Kunz (2015)
Functionalization of platinum nanoparticles with L-proline: simultaneous enhancements of catalytic activity and selectivity.Journal of the American Chemical Society, 137 2
J. Ristein, R. Stief, L. Ley, W. Beyer (1998)
A comparative analysis of a-C:H by infrared spectroscopy and mass selected thermal effusionJournal of Applied Physics, 84
Carolyn Schoenbaum, D. Schwartz, J. Medlin (2014)
Controlling the surface environment of heterogeneous catalysts using self-assembled monolayers.Accounts of chemical research, 47 4
P. Sonstroem, D. Arndt, Xiaodong Wang, V. Zielasek, M. Bäumer (2011)
Ligand capping of colloidally synthesized nanoparticles--a way to tune metal-support interactions in heterogeneous gas-phase catalysis.Angewandte Chemie, 50 17
J. Benitez, M. San-Miguel, S. Domínguez-Meister, J. Heredia-Guerrero, M. Salmeron (2011)
Structure and Chemical State of Octadecylamine Self-Assembled Monolayers on MicaJournal of Physical Chemistry C, 115
I. Prosanov, A. Matvienko (2010)
Study of PVA thermal destruction by means of IR and Raman spectroscopyPhysics of the Solid State, 52
(2011)
Bäumer, Angew.C hem. Int
L. Altmann, S. Kunz, M. Bäumer (2014)
Influence of Organic Amino and Thiol Ligands on the Geometric and Electronic Surface Properties of Colloidally Prepared Platinum NanoparticlesJournal of Physical Chemistry C, 118
Hongfeng Yin, Zhen Ma, M. Chi, S. Dai (2010)
Activation of Dodecanethiol-Capped Gold Catalysts for CO Oxidation by Treatment with KMnO4 or K2MnO4Catalysis Letters, 136
Younan Xia, Y. Xiong, Byungkwon Lim, S. Skrabalak (2009)
Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics?Angewandte Chemie, 48 1
F. Lytle, P. Wei, R. Greegor, G. Via, J. Sinfelt (1979)
Effect of chemical environment on magnitude of x‐ray absorption resonance at LIII edges. Studies on metallic elements, compounds, and catalystsJournal of Chemical Physics, 70
Hyunjoon Song, R. Rioux, J. Hoefelmeyer, Russell Komor, K. Niesz, Michael Grass, P. Yang, G. Somorjai (2006)
Hydrothermal growth of mesoporous SBA-15 silica in the presence of PVP-stabilized Pt nanoparticles: synthesis, characterization, and catalytic properties.Journal of the American Chemical Society, 128 9
N. Zheng, G. Stucky (2006)
A general synthetic strategy for oxide-supported metal nanoparticle catalysts.Journal of the American Chemical Society, 128 44
L. Daasch, D. Smith (1951)
Infrared Spectra of Phosphorus CompoundsAnalytical Chemistry, 23
Junling Zhang, Y. Wang, Hua Ji, Yongge Wei, N. Wu, Bojun Zuo, Qilong Wang (2005)
Magnetic nanocomposite catalysts with high activity and selectivity for selective hydrogenation of ortho-chloronitrobenzeneJournal of Catalysis, 229
Guangxu Chen, Chaofa Xu, Xiaoqing Huang, Jinyu Ye, L. Gu, Gang Li, Zi-Chao Tang, Binghui Wu, Huayan Yang, Zipeng Zhao, Zhiyou Zhou, G. Fu, N. Zheng (2016)
Interfacial electronic effects control the reaction selectivity of platinum catalysts.Nature materials, 15 5
A. Muleja, X. Mbianda, R. Krause, K. Pillay (2012)
Synthesis, characterization and thermal decomposition behaviour of triphenylphosphine-linked multiwalled carbon nanotubesCarbon, 50
Chao Lian, Hong-qiang Liu, Chaoxian Xiao, Wen Yang, Kai Zhang, Yan Liu, Y. Wang (2012)
Solvent-free selective hydrogenation of chloronitrobenzene to chloroaniline over a robust Pt/Fe3O4 catalyst.Chemical communications, 48 25
B. Coq, A. Tijani, R. Dutartre, F. Figuéras (1993)
Influence of support and metallic precursor on the hydrogenation of p-chloronitrobenzene over supported platinum catalystsJournal of Molecular Catalysis, 79
(1999)
Dean in Lange’s Handbook of Chemistry, McGraw-Hill
Minghui Liang, Xiaodong Wang, Hong-qiang Liu, Haichao Liu, Yuan Wang (2008)
Excellent catalytic properties over nanocomposite catalysts for selective hydrogenation of halonitrobenzenesJournal of Catalysis, 255
Lihui Xin, Yue Wang, Liqun Li, Wenqing Huang, Zicheng Xiao, Pingfan Wu, Wenbo Zhao, Wei Guo, Peng Jiang, Minghui Liang (2017)
Deficient copper decorated platinum nanoparticles for selective hydrogenation of chloronitrobenzeneJournal of Materials Chemistry, 5
M. Mason (1983)
Electronic structure of supported small metal clustersPhysical Review B, 27
“Unprotected” Pt nanocrystals were modified with triphenylphosphine (PPh3), octadecylamine (ODA), poly(vinylpyrrolidone) (PVP), poly(vinyl alcohol) (PVA), and dodecanethiol (DT) to investigate the effect of protective agents on the intrinsic catalytic property of Pt nanocrystals. By evaluating the catalytic performance of these model catalysts for the hydrogenation of para‐chloronitrobenzene (p‐CNB), it was found that direct or indirect interaction between nanocrystals and protective agents imposed a great impact on the catalytic performance of the nanocrystals. Protective agents with different electron‐donating ability (PPh3, ODA, PVP, and PVA) directly altered surface electronic state of Pt nanocrystals to bring the surface Pt atoms into an electron‐rich state, which would exert influence on the hydrogenation course by changing the adsorption and the reactivity of reactant, intermediates, and products. In contrast, DT exerted an indirect influence on the Pt nanocrystals. The coordinated Pt atoms were oxidized by DT to generate cationic Pt species on the surface of nanocrystals, and the cationic species would simultaneously improve the hydrogenation rate and selectivity to para‐chloroaniline by polarizing the N=O bond in the −NO2 group of p‐CNB and altering the electronic state of Pt nanocrystals, respectively. This work provided further insights into nanocatalysis, which is helpful for further design and application of highly efficient nanocrystal catalysts.
ChemCatChem – Wiley
Published: Jul 7, 2018
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.