Reaction of Ph2SbCl3 with 2,2′‐bipyridine and Me3SiOSO2CF3 releases chlorobenzene, which is interpreted as a reductive (SbV/SbIII) elimination from a complex of a stiboranium cation. Conversely, reactions of Ph2SbCl3 with 4‐methylpyridine‐N‐oxide and AgOSO2CF3 give redox‐resistant complexes with the generic formulae [Ph2SbCl3−xLx+1][OTf]x, including a compound containing a pnictogen(V) trication.
Chemistry - A European Journal – Wiley
Published: Jan 15, 2018
Keywords: ; ; ;
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