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B. Moulton, M. Zaworotko (2001)
From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.Chemical reviews, 101 6
I. Hamachi, A. Fujita, T. Kunitake (1997)
Protein Engineering Using Molecular Assembly: Functional Conversion of Cytochrome c via Noncovalent InteractionsJournal of the American Chemical Society, 119
Blue crystals of the title compound, (Cu(C8H3O7S)(C4H11N2)(H2O))n, were obtained from the slow diffusion of a methanol solution of piperazine into an aqueous solution of sodium 5‐sulfoisophthalate and copper nitrate. The CuII ion coordination is composed of two O atoms from two trianionic 5‐sulfoisophthalic acid ligands, one N atom from the piperazinium cation and one water O atom in a distorted square‐planar geometry. The Cu2+ ions are bridged by the sulfonate–carboxylate ligands to form a zigzag chain. Hydrogen bonds and π–π interactions among the chains produce a three‐dimensional hydrogen‐bonded architecture.
Acta Crystallographica Section E – Wiley
Published: Oct 1, 2005
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