C–O Bonds from Pd‐Catalyzed C(sp3)–H Reactions Mediated by Heteroatomic Groups

C–O Bonds from Pd‐Catalyzed C(sp3)–H Reactions Mediated by Heteroatomic Groups This review summarizes Pd‐catalyzed procedures leading to single C–O bonds from aliphatic C–H bonds of substrates bearing heteroatomic groups. Coordination of the latter to PdII species favors the activation of a C(sp3)–H bond and controls the regioselectivity, leading to a palladacycle as intermediate. Either PdII–Pd0 or PdII–PdIV redox catalytic cycles, possibly with a PdIII intermediate, might be involved, depending on the directing group and the oxidant. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png European Journal of Organic Chemistry Wiley

C–O Bonds from Pd‐Catalyzed C(sp3)–H Reactions Mediated by Heteroatomic Groups

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Publisher
Wiley
Copyright
© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1434-193X
eISSN
1099-0690
D.O.I.
10.1002/ejoc.201701446
Publisher site
See Article on Publisher Site

Abstract

This review summarizes Pd‐catalyzed procedures leading to single C–O bonds from aliphatic C–H bonds of substrates bearing heteroatomic groups. Coordination of the latter to PdII species favors the activation of a C(sp3)–H bond and controls the regioselectivity, leading to a palladacycle as intermediate. Either PdII–Pd0 or PdII–PdIV redox catalytic cycles, possibly with a PdIII intermediate, might be involved, depending on the directing group and the oxidant.

Journal

European Journal of Organic ChemistryWiley

Published: Jan 14, 2018

Keywords: ; ; ; ; ; ; ;

References

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