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Benzyl 2‐deoxy‐2‐(3,5‐di‐ tert ‐butylsalicylamino)‐α‐ d ‐glucopyranoside

Benzyl 2‐deoxy‐2‐(3,5‐di‐ tert ‐butylsalicylamino)‐α‐ d ‐glucopyranoside The title compound, C28H41NO6, was obtained by reduction of benzyl 2‐deoxy‐2‐(3,5‐di‐tert‐butylsalicylideneamino)‐α‐d‐glucopyranoside. The benzyl substituent is in an axial position, whereas the 3,5‐di‐tert‐butylsalicylamino substituent and the hydroxyl groups are in equatorial positions. The enantiomerically pure title compound is a potential O,N,O‐chelate ligand suitable as a precursor for chiral transition metal complexes. The absolute configuration was determined by NMR experiments. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section E Wiley

Benzyl 2‐deoxy‐2‐(3,5‐di‐ tert ‐butylsalicylamino)‐α‐ d ‐glucopyranoside

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References (5)

Publisher
Wiley
Copyright
Copyright © 2007 Wiley Subscription Services, Inc., A Wiley Company
ISSN
1600-5368
eISSN
1600-5368
DOI
10.1107/S1600536807023574
Publisher site
See Article on Publisher Site

Abstract

The title compound, C28H41NO6, was obtained by reduction of benzyl 2‐deoxy‐2‐(3,5‐di‐tert‐butylsalicylideneamino)‐α‐d‐glucopyranoside. The benzyl substituent is in an axial position, whereas the 3,5‐di‐tert‐butylsalicylamino substituent and the hydroxyl groups are in equatorial positions. The enantiomerically pure title compound is a potential O,N,O‐chelate ligand suitable as a precursor for chiral transition metal complexes. The absolute configuration was determined by NMR experiments.

Journal

Acta Crystallographica Section EWiley

Published: Jun 1, 2007

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