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Application of the Solvent Dimethyl Sulfoxide/Tetrabutyl‐Ammonium Acetate as Reaction Medium for Mix‐Acylation of Pulp

Application of the Solvent Dimethyl Sulfoxide/Tetrabutyl‐Ammonium Acetate as Reaction Medium for... An important cellulose mixed ester, cellulose acetate butyrate (CAB), was successfully prepared in tetrabutylammonium acetate (TBAA)/dimethyl sulfoxide (DMSO) system. The structure of the cellulose derivative was characterized with a Fourier Transform IR spectrometer and analyzed using 13C cross‐polarization magic angle spinning nuclear magnetic resonance. The degree of substitution (DS) of the samples prepared was calculated according to 1H‐NMR analysis. And the solubility of CAB was investigated in a wide range of traditional organic solvents such as 2‐methyl‐ethyl ketone, dichloromethane and ethyl acetate. The thermal properties of the product were analyzed by TGA analysis. The surface morphology of the esters was characterized with a field emission‐scanning electron microscopy (FE‐SEM). The relationship among surface morphology, solubility, and DS of the cellulose mixed ester was discussed. Moreover, TBAA and DMSO were recovered by vacuum distillation, which was characterized by Fourier transform infrared spectroscopy. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Advances in Polymer Technology Wiley

Application of the Solvent Dimethyl Sulfoxide/Tetrabutyl‐Ammonium Acetate as Reaction Medium for Mix‐Acylation of Pulp

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Publisher
Wiley
Copyright
Copyright © 2018 Wiley Periodicals, Inc.
ISSN
0730-6679
eISSN
1098-2329
DOI
10.1002/adv.21742
Publisher site
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Abstract

An important cellulose mixed ester, cellulose acetate butyrate (CAB), was successfully prepared in tetrabutylammonium acetate (TBAA)/dimethyl sulfoxide (DMSO) system. The structure of the cellulose derivative was characterized with a Fourier Transform IR spectrometer and analyzed using 13C cross‐polarization magic angle spinning nuclear magnetic resonance. The degree of substitution (DS) of the samples prepared was calculated according to 1H‐NMR analysis. And the solubility of CAB was investigated in a wide range of traditional organic solvents such as 2‐methyl‐ethyl ketone, dichloromethane and ethyl acetate. The thermal properties of the product were analyzed by TGA analysis. The surface morphology of the esters was characterized with a field emission‐scanning electron microscopy (FE‐SEM). The relationship among surface morphology, solubility, and DS of the cellulose mixed ester was discussed. Moreover, TBAA and DMSO were recovered by vacuum distillation, which was characterized by Fourier transform infrared spectroscopy.

Journal

Advances in Polymer Technology – Wiley

Published: Jun 1, 2018

Keywords: ; ; ;

References